摘要： 采用预乳化工艺，半连续种子聚合法，通过磷酸丙烯酸酯(P-A)、甲基丙烯酸甲酯(MMA)、苯乙烯(St)、 丙烯酸丁酯(BA)、丙烯酸(AA)共聚反应制得具有高附着力的改性苯 -丙乳液。结果表明，当磷酸丙烯酸酯在乳液聚 合中占单体总量的 5%时，乳液涂膜在铝板、镀锌板、马口铁、ABS、PVC、玻璃板等基材上的附着力从 3~5级提高到 0 ~1级，在玻璃上的硬度从 H提高到 2H，耐水性从 12h提高到 192h，同时对乳液的聚合稳定性、Ca2+稳定性都有一定 的改善。
关键词:
磷酸丙烯酸酯,
共聚反应,
附着力,
耐水性,
改性苯-丙乳液
Abstract: A modified stryrene-acryli cemulsions with strong adhesion were prepared with the help of copol-ymerization of P-A、MMA、St、BA、AA by means of pre-emulsification technology and semi-continuou ssed e-mulsion polymerization.The results showed that when the adition amount of phosphoric acrylateis5%，the ad-hesion strength of film on aluminum，shet，galvanized sheet，tin-plate，ABS，PVC，glass plate，etc.can be improved from grade3~5 to grade0~1，the hardnes on glas from H to 2H and and water-resistance of coat-ing from 12h to 192h，which also could improve polymerization stability and Ca2+ stability of emulsion.
Key words:
Phosphoric acrylate,
copolymerization reaction,
adhesion strength,
water-resistance,
modi-fied stryrene-acrylic emulsion
陈能昌, 梁 亮, 谭卓华, 邓旭忠. 磷酸丙烯酸酯共聚改性苯丙乳液的研究[J]. 涂料工业, 2008, 38(9): 30-32.
Chen Nengchang, Liang Liang, Tan Zhuohua, Deng Xuzhong. Study on Modification of Stryrene-Acrylic Emulsion with Phosphoric Acrylate[J]. Paint & Coatings Industry, 2008, 38(9): 30-32.