涂料工业 ›› 2015, Vol. 45 ›› Issue (3): 33-36.

• 工艺技术 • 上一篇    下一篇

环境友好型无铜自抛光防污涂料的制备与性能研究

曹京宜1 ,张海永1 ,孟宪林1 ,憨化景2 ,陈蓉蓉2 ,刘连河2,3 ,王乐乐2 ,王 君2   

  1. 1、 91872 部队海军涂料分析检测中心,北京 102442; 2、哈尔滨工程大学海洋先进 材料研究院,哈尔滨 150001; 3、青岛海洋新材料科技有限公司,山东青岛 266100
  • 出版日期:2015-03-31 发布日期:2019-05-31
  • 作者简介:曹京宜( 1972—) ,女,博士,高级工程师,主要从事船舶防护涂料及分析检测研究。
  • 基金资助:
    总装预研基金;科技部国家国际合作专项(2013DFA50480)

Preparation and Property of Environmental Friendly Copper-Free Self-Polishing Antifouling Coatinngs

Cao Jingyi1, Zhang Haiyong1, Meng Xianlin1, Han Huajing2, Chen Rongrong 2, Liu Lianhe 2,3, Wang lele2, wang Jun2   

  1. 1. Naval Coatings Analysis and Testing Centre Force 91872, Beijing 102442,China; 2. Intitute of Advanced Marine Materials, Harbin Engineering University, Harbin 150001,China; 3. Qingdao Advanced Marine Material Technology Co., Ltd., Qingdao, Shandong 266100,China
  • Online:2015-03-31 Published:2019-05-31

摘要: 以自制丙烯酸锌树脂为主要成膜物,加入吡啶硫酮锌( ZnPT) 和吡啶三苯基硼烷( PK) 这2 种有机防污剂及填料等配制成无铜自抛光防污涂料。 分析了有机防污剂含量对涂料基本性能的影响;通过防污涂料浅海浸泡实验考察涂料在实际海洋环境中的防污性能。 结果表明:当 ZnPT 与 PK 的质量比为 6 ∶4时,无铜丙烯酸锌基防污涂料具有良好的防污性能。

关键词: 海洋防污, 无铜, 吡啶硫酮锌, 吡啶三苯基硼烷

Abstract: Driven by the increasingly stringent requirements on environmental protection, the need for development of copper-free self-polishing antifouling coatings has been highlighted. In this study, the environmental friendly copper-free self-polishing antifouling coatings have been prepared from zinc-acrylate polymer as matrix, Zinc 2-pyridinethiol-1-oxide (ZnPT) and Pyridine triphenyl borane (PK) as biocides and other pigments. The basic properties of the antifouling coatings with different organic biocides are studied. Meanwhile, the antifouling property of the prepared coatings has been compared with that of the similar imported product via offshore immersion test. The results show that the title coatings comprising ZnPT and PK at mass ratio of 6: 4 can exhibit excellent antifouling property.

Key words: marine antifouling, copper-free, Zinc 2-pyridinethiol-1-oxide, pyridine triphenyl borane