涂料工业 ›› 2025, Vol. 55 ›› Issue (12): 23-29. doi: 10.12020/j.issn.0253-4312.2025-327

• 工艺技术 • 上一篇    下一篇

环氧改性有机硅涂层的制备及防冰稳定性研究

张乐乐,郑钦文,涂书画,冯 杰*   

  1. 浙江工业大学材料科学与工程学院,先进分离膜材料全国重点实验室,杭州310000
  • 出版日期:2025-12-01 发布日期:2025-12-26

Preparation and Anti-icing Stability of Epoxy-modified Silicone Coating

ZHANG Lele,ZHENG Qinwen,TU Shuhua,FENG Jie   

  1. Laboratory of Advanced Separation Membrane Materials and College of Materials Science and Engineering,Zhejiang
    University of Technology,Hangzhou 310000,China
  • Online:2025-12-01 Published:2025-12-26

摘要: 【目的】结冰现象对飞机、风电叶片及高速列车等装备的安全运行构成严重威胁,开发兼具低冰黏附强度与优异力学稳定性的防护涂层具有重要意义。【方法】本研究将环氧树脂与聚酰胺、端羟基聚二甲基硅氧烷及 KH560复合,构建了一种环氧改性有机硅涂层体系。该体系在保留有机硅材料本征防冰性能的基础上,显著提升了涂层的力学强度。【结果】所制备的环氧改性有机硅涂层具备良好的疏水性与低表面能特性。即使在砂蚀后,涂层仍能维持结构完整性及稳定的防冰性能。此外,该涂层在铝材表面表现出优异的附着力,最高可达 4B等级,并与环氧底漆之间形成良好的界面结合力。【结论】本研究成功实现了有机硅防冰性能与环氧树脂力学优势的有机结合,为高速列车底部等严寒环境下的防冰保护提供了可行的技术解决方案。

关键词: 防冰, 有机硅涂层, 环氧树脂, 力学性能, 低表面能

Abstract: [Objective]Icing seriously threatens the safe operation of equipment such as aircraft, wind turbine blades,and high-speed trains,making it essential to develop protective coating thatexhibit both low ice-adhesion strength with excellent mechanical stability.[Methods]In this study,an epoxy-modified silicone coating system was constructed by incorporating epoxy resin with polyamide, hydroxyl-terminated polydimethylsiloxane,and KH560. In this system,the inherent anti-icing property of silicone materials was preserved,while the mechanical strength of the coating was significantly enhanced.[Results]The prepared epoxy-modified silicone coating exhibited good hydrophobicity andlow surface energy. Even after sand erosion,the coating retained its structural integrity and stable anti-icing performance. Moreover,it demonstrated excellent adhesion on aluminum substrates,reaching a maximum rating of 4B,and formed strong interfacial bonding with an epoxy primer.[Conclusion]The anti-icing properties of silicone and the mechanical advantages of epoxy resin were successfullyintegrated in this work,providing a feasible technical solution for ice protection in extreme coldenvironments such as the underbodies of high-speed trains.

Key words: anti-icing, silicone coating, epoxy resin, mechanical properties, low surface energy

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