涂料工业 ›› 2014, Vol. 44 ›› Issue (9): 1-5.

• 探索开发 •    下一篇

环保型耐高温涂料的应用及高温褪色机理研究

张 昕1,2,王梦心3,李 群3,郑 峰1,4,韩 金1,赵文杰1,乌学东1   

  1. 1、中国科学院海洋新材料与应用技术重点实验室、浙江省海洋材料与防护技术重点实验室,中国科学院宁波材料技术与工程研究所,浙江宁波 315201;2、中国科学院兰州化学物理研究所固体润滑国家重点实验室,兰州 730000;3、宁波大达化学有限公司,浙江宁波 315040;4、上海应用技术学院,上海 200235
  • 出版日期:2014-09-01 发布日期:2019-05-30
  • 作者简介:张昕(1978—),女,高级工程师,从事高温、防腐涂料及相关领域的研究工作。
  • 基金资助:
    浙江省自然科学基金(批准号:LY13E090009); 固体润滑国家重点实验室(中国科学院兰州化学物理研究所)开放课题(1104); 国家自然科学青年基金资助项目(51303192); 宁波市重大科技专项(2013B6013)

Applications of Environmental Friendly High Temperature Coatings and Fading Mechanism under High Temperature

Zhang Xin1,2, Wang Mengxin3, Li Qun3, Zhang Feng1,4 Han Jin1,Zhao Wenjie1,Wu Xuedong1   

  1. 1. Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protectire Technologies, Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences, Ningbo, Zhejiang 315201 China; 2. State Key Laboratory of Solid Lubrication, Lanchou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China; 3. Ningbo Dada Chemical Co.,Ltd., Ningbo, Zhejiang 315010,China; 4. Shanghai Institution of Technology, Shanghai 200235, China
  • Online:2014-09-01 Published:2019-05-30

摘要: 利用有机硅树脂作为耐高温材料制备性能优良的耐高温涂料,通过TG、SEM、紫外积分球法等测试考察了原材料的耐热性、耐高温涂层的耐温性能以及高温煅烧后涂层的颜色变化情况,从而进一步研究耐高温涂层在高温煅烧后的高温褪色机理。结果表明:耐高温涂层在高温煅烧后,由于有机硅树脂分解为白色细小的无机SiO2颗粒覆盖在涂层表面,从而使得涂层黑度降低,颜色变浅。

关键词: 有机硅, 耐高温涂料, 耐热机理

Abstract: Silicone resins were used as high temperature resistant raw materials to prepare high temperature coatings with good properties. Thermal resistance of raw materials and coating thereof, and color difference under high temperature were characterized by TG, SEM and in-tegrating-sphere photometer. Meanwhile, the fading mechanism under high temperature was investigated. The results showed that the high temperature caused a decomposition of the silicone resin and thus white fine particles of SiO2 were formed on the surface of the coating,which diluted the color of the said coating.

Key words: silicon resin, heat resisting property coating, heat-resistant mechanism