摘要： 采用自由基聚合法,合成了氟硅改性苯乙烯环氧丙烯酸树脂,其中硅以硅溶胶的形式,将无机网络引入到聚合物网络体系中,形成有机-无机杂化材料。通过对涂膜的附着力、耐冲击性、接触角等各项性能的研究,得到合成树脂的最佳配比为:软硬单体比为0.8,含氟单体含量为12%,环氧含量为10%,苯乙烯含量为10%,丙烯酸含量为6%。并且考察了无机硅溶胶对涂膜化学稳定性能的影响、涂层表面氟原子含量以及涂膜与水接触角。通过添加纳米SiO₂,制备了具有微纳米阶层型结构的涂层,其与水的接触角可达150°,具有超疏水特性。

关键词: 自由基聚合, 有机-无机杂化材料, 微纳米阶层型结构, 超疏水特性

Abstract: The title fluorine/silicone modified styrene epoxy acrylic resin was synthesized by radical polymerization. in which silicon(as silica sol )containing inorganic networks was introduced into the organic network system forming a organi-inorganic hybrid system. Through tests of adhesion, impact resistance, and water contact angle, etc, an optimum formula for synthetic polymer was obtained: hard and soft monomer ratio 0.8, amount of fluoride monomer 12%, epoxy content 10%, styrene content 10%, acrylic acid content 6%. The influence of the inorganic silica sol on chemical stability, and the influence of the content of fluorine atom on contact angle with water was investigated. By adding nano-SiO₂,a micro-nano class structure of the coating with super-hydrophobic properties was developed, with water contact angle up to 150°.

Key words: radical polymerization, organic-inorganic hybrid materials, micro-nano class structure, superhydrophobic properties