涂料工业 ›› 2010, Vol. 40 ›› Issue (5): 71-73.

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电子活化再生原子转移自由基聚合的研究进展

杨兴兵,张立武,刘 静,沈进明,李圆圆,郑 妍   

  1. 1. 重庆大学化学化工学院,重庆 400044;2. 重庆文理学院文学与传媒学院,重庆 402168
  • 出版日期:2010-05-01 发布日期:2019-05-15

Research Progress of Activator Generated by Electron Transfer for Atom Transfer Radical Polymerization

Yang Xingbing1, Zhang Liwu1, liu Jing2, Shen Jinming1, Li Yuanyuan1, Zheng Yan1   

  1. 1. College of Chemistry and Chemical Engineering, Chongqing University, Chongging 400044, China; 2. Chongging University of Arts and Sciences, Chongging 402168, China
  • Online:2010-05-01 Published:2019-05-15

摘要: 原子转移自由基聚合是一种新兴的活性/可控聚合方法,AGET ATRP是在 ATRP的基础上改进而发展起来的活性聚合方法。介绍了 AGET ATRP的基本机理及研究进展,以及所用催化剂、引发剂、还原剂的研究情况,并展望了其发展前景。

关键词: 电子活化再生原子转移自由基聚合(AGET ATRP), 催化剂, 引发剂, 还原剂, 机理

Abstract:

Atom transfer radical polymerization (ATRP) is a new living/controlled polymerization, and Activator Generated by Electron Transfer for atom transfer radical polymerization(AGET ATRP) is derived on the basis of ATRP.This paper introduced the mechanism and research progress of AGET ATRP,focusing on catalyst,initialor and reductant systems.The research prospect of AGET ATRP was proposed.

Key words: activator generated by electron transfer atom transfer radical polymerization(AGET ATRP), catalysts, initiators, mechanism, reductant