巯基点击反应制备双重固化的水性混杂涂料

涂料工业 ›› 2012, Vol. 42 ›› Issue (3): 20-23.

巯基点击反应制备双重固化的水性混杂涂料

付长清^1，2，陈樟²，刘海波²，陈义旺¹，申亮²

1、南昌大学高分子研究所，南昌 330031; 2、江西科技师范学院江西省有机功能分子重点实验室，南昌 330013

出版日期:2012-03-31 发布日期:2019-05-31
作者简介:付长清(1980—)，女，在读博士，研究方向为水性光固化涂料。
基金资助:
国家自然科学基金项目(51063002)、江西省教育厅青年科学基金项目(GJ09575)

Preparation of Waterborne Dual Curing Hybrid Coating via Thiol Based Click Reaction

Fu Changqing ^1,2, Chen Zhang², Liu Haibo²,Chen Yiwang¹, Shen Liang²

1. Institute of Polymers, Nanchang University, Nanchang 330031, China; 2. Jiangxi Key Laboratory of Organic Chemistry Jiangxi Science Technology Normal Unicersity, Nanchang 330013, China

Online:2012-03-31 Published:2019-05-31

摘要/Abstract

摘要： 通过可逆加成 -断裂链转移自由基(RAFT)乳液聚合的方法合成了一系列具有不同烯丙基 /环氧基物质的量比的水性混杂乳液，将此混杂乳液与巯基封端的聚氨酯水分散体复合可制得含烯丙基 /环氧基 /巯基三种活性基团的水性混杂涂料，采用傅里叶红外光谱(FT-IR)对 RAFT乳液和固化膜的结构及混杂涂料的固化过程进行研究，并研究了固化膜的性能。研究表明可通过 RAFT乳液聚合制得具有预想结构的聚合物乳液，不同的固化条件对固化膜的性能有很大影响，在光 /热双重固化的条件下，通过巯基点击反应制备的涂膜铅笔硬度为 6H，耐甲乙酮的擦拭次数为10次，凝胶量为 83.96%，耐冲击性 >50cm

关键词: 混杂, RAFT乳液聚合, 巯基点击反应, 双重固化

Abstract:

A series of waterbome hybrid emulsion with different mole ratio of allyl/epoxy were prepared through the reversible addition -fragmentation chain transfer radical (RAFT) emulsion polymerization,which were then blended with thiol terminated water-based polyurethane dispersion to obtain the waterbone hybrids coatings which containing allyl epoxy/thiol three active groups. The structures of the emulsions and cured films and the curing process of hybrid coatings were characterized by FT-IR, at the same time,the properties of cured films were studied. The results showed that the emulsions with expected with expected structure could be prepared through the RAFT emulsion polymerization, and the properties of cured films varied with different curing condition. Under UV/thermo dual curing conditions, the gel content of cured films was 83. 96%, the solvent-resistance(MEK)was 1 000 time, pencil hardness 6H, and impact strength was greater than 50 cm.

Key words: hybrid, RAFT emulsion polymerization, thiol based click reaction, dual curing

付长清, 陈樟, 刘海波, 陈义旺, 申亮. 巯基点击反应制备双重固化的水性混杂涂料[J]. 涂料工业, 2012, 42(3): 20-23.

Fu Changqing, Chen Hansa Liu Haibo Chen Yiwang, Shen Liang. Preparation of Waterborne Dual Curing Hybrid Coating via Thiol Based Click Reaction[J]. Paint & Coatings Industry, 2012, 42(3): 20-23.

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