涂料工业 ›› 2009, Vol. 39 ›› Issue (4): 41-44.

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固化剂对环氧乳液型防火涂料性能的影响

王国建1,2,杨 姝2   

  1. 1、先进土木工程材料教育部重点实验室,上海 200092; 2、同济大学材料科学与工程学院,上海 200092
  • 出版日期:2009-04-01 发布日期:2019-05-31
  • 作者简介:王国建(1953—),男,教授,博士生导师,主要从事高分子活性聚合、高分子功能材料、高分子化学建材、涂料等方面的教学和研究。
  • 基金资助:
    国家高技术研究发展计划(863计划)项目,编号:2006AA03Z463

Influence of Curing Agents on Epoxy Emulsion-based Intumescent Fire Retardant Coatings

Wang Guojian1,2,Yang Shu2   

  1. 1. Key Laboratory of Adnanced Ciwi Engineering Materials, Ministry of Education, Shanghai 200092,china;2. School of Materials Science and Engineering, Tongi University, Shanghai 200092, China
  • Online:2009-04-01 Published:2019-05-31

摘要: 以环氧乳液为基料,聚磷酸铵、三聚氰胺、季戊四醇(APP/MEL/PER)为防火助剂研制了超薄膨胀型钢结构防火涂料。通过调整环氧乳液/固化剂比例改变涂层的性能,研究了固化剂用量对涂料防火性能的影响。通过热分析讨论了防火助剂和环氧涂膜的分解过程及协同作用。结果表明,固化剂占环氧乳液含量15%~20%时,涂层的力学性能和防火性能均较好。

关键词: 钢结构 , 膨胀型防火涂料 , 环氧乳液 , 固化剂

Abstract: Ultrathin intumescent fire-retardant coatings based on epoxy emulsion as binder were pre-pared, together with ammonium poly phosphate, melamine and pentaerythritol(APP/MEL/PER). The prop-erties of the coatings were controlled by adjusting the ratio of the emulsion and the corresponding curing a-gent.The influence of the curing agent amount on the fire retardance of the coatings was investigated. TGA and DSC were used to analyse the decomposition process and the synergistic effect between binder and APP/ MEL/PER. The results showed that the coating has better mechanical and fireretardant properties when the dosage of curing agent was 15%-20% of the expoxy emulsion.

Key words: steel structure, intumescent fireretardant coating, epoxy emulsion, curing agent