Preparation and Properties of Bio-Based Thiol-Ene UV Curing Coating

doi:10.12020/j.issn.0253-4312.2018.2.43

Paint & Coatings Industry ›› 2018, Vol. 48 ›› Issue (2): 43-49. doi: 10.12020/j.issn.0253-4312.2018.2.43

• HSE • Previous Articles Next Articles

Preparation and Properties of Bio-Based Thiol-Ene UV Curing Coating

Hu Yunyong^1,²,Fu Changqing^1,²,Shen Liang^1,^2,^*

^1. Department of Polymer and Coating, Jiangxi Science & Technology Normal University, Nanchang 330013,China;
^2. Jiangxi Engineering Laboratory of Waterborne Coating, Nanchang 330013,China

Received:2017-12-15 Online:2018-02-02 Published:2018-09-18
Contact: Liang Shen

生物基巯基-烯UV固化涂膜的制备及性能研究

胡云勇^1,²,付长清^1,²,申亮^1,^2,^*

^1. 江西科技师范大学化学化工学院涂料与高分子系,南昌 330013
^2. 江西省水性涂料工程实验室,南昌 330013

通讯作者: 申亮
基金资助:
国家自然科学基金(51563011);江西省自然科学基金(2016BAB203094);江西省教育厅科研项目(GJJ160775);江西科技师范大学校拔尖人才项目(2016QNBJRC007);江西科技师范大学研究生创新专项资金项目资助(YC2016-X04)

Abstract

Abstract:

A series of UV curable monomers (GAM, SOM and COT) were prepared by simple green process using gallic acid, epoxidized soybean oil and castor oil as raw materials. Those monomers were then used to prepare a series UV curing coating via thiol-ene UV curing process. The structure of the monomers and the properties of films were characterized by nuclear magnetic resonance (NMR), thermogravimetric analyzer (TGA), differential scanning calorimetry (DSC) and dynamic mechanical analyzer (DMA). The effect of different monomer content on coating mechanical properties and thermal properties was studied. The results showed that the pencil hardness and glass transition temperature of the UV curing coating had been improved with the increase of the content of GAM, and all of the bio-based coating had good thermal stability.

Key words: gallic acid, epoxidized soybean oil, castor oil, thiol-ene, UV curing coating

摘要：

以没食子酸、环氧大豆油和蓖麻油为原料,通过简单绿色的工艺制备了一系列可UV固化活性单体(GAM、SOM、COT), 并将所制备的单体进行巯基-烯UV固化,制得一系列可再生碳含量较高的UV固化涂膜。通过核磁( ¹H NMR)、热重分析仪(TGA)、差示扫描量热仪(DSC)、动态机械分析仪(DMA)对单体结构和膜的性能进行了表征分析,并研究了不同单体含量对涂膜机械性能、玻璃化转变温度(T_g)以及热性能的影响。结果表明:随着没食子酸基单体含量增加,UV固化涂膜的铅笔硬度和T_g有所提升,涂膜整体具有较好的热稳定性。

关键词: 没食子酸, 环氧大豆油, 蓖麻油, 巯基-烯, UV固化涂层

CLC Number:

TQ637.83

Hu Yunyong,Fu Changqing,Shen Liang. Preparation and Properties of Bio-Based Thiol-Ene UV Curing Coating[J]. Paint & Coatings Industry, 2018, 48(2): 43-49.

胡云勇,付长清,申亮. 生物基巯基-烯UV固化涂膜的制备及性能研究[J]. 涂料工业, 2018, 48(2): 43-49.

/ / Recommend / Download Citations

URL: https://www.cn-pci.com/EN/10.12020/j.issn.0253-4312.2018.2.43

https://www.cn-pci.com/EN/Y2018/V48/I2/43

References

[1]	IONESCU M, RADOJ?I? D, WAN X M , et al. Functionalized vegetable oils as precursors for polymers by thiol-ene reaction [J]. European Polymer Journal, 2015,67:439-448.
[2]	BA?TüRK E, DENIZ D Y, KAHRAMAN M V . Preparation of thiol-ene based photo-crosslinked polymer as a potential phase change material[J]. Materials Chemistry and Physics, 2016,177:521-528.
[3]	李鹏, 马松琪, 焦纬洲 , 等. 植物油基紫外光固化涂料研究进展[J]. 涂料工业, 2016,46(5):81-87.
[4]	MA S Q, JIANG Y H, LIU X Q , et al. Bio-based tetrafunctional crosslink agent from gallic acid and its enhanced soybean oil-based UV-cured coatings with high performance[J]. RSC Advances, 2014,4(44):23036-23042.
[5]	MIAO S D, ZHANG S P, SU Z G , et al. A novel vegetable oil-lactate hybrid monomer for synjournal of high-T_g polyurethanes[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2010,48(1):243-250.
[6]	LIU R, ZHENG J C, GUO R X , et al. Synjournal of new biobased antibacterial methacrylates derived from tannic acid and their application in UV-cured coatings[J]. Industrial & Engineering Chemistry Research, 2014,53(27):10835-10840.
[7]	ZHANG H, YANG L T, LI Y T , et al. Preparation and properties of soybean oil-based curing agents for epoxy resin[J]. Journal of Applied Polymer Science, 2017,134(17):44754.
[8]	DAI J Y, LIU X Q, MA S Q , et al. Soybean oil-based UV-curable coatings strengthened by crosslink agent derived from itaconic acid together with 2-hydroxyethyl methacrylate phosphate[J]. Progress in Organic Coatings, 2016,97:210-215.
[9]	王青, 陈广学, 余明光 , 等. 蓖麻油基巯烯基紫外光固化胶粘剂的研制与性能研究[J]. 影像科学与光化学, 2017,35(1):46-52.
[10]	洪勇波, 王念贵 . 大豆油基UV固化涂料的制备和表征[J]. 胶体与聚合物, 2017 ( 1):32-34.
[11]	LIU R, LUO J, ARIYASIVAM S , et al. High biocontent natural plant oil based UV-curable branched oligomers[J]. Progress in Organic Coatings, 2017,105:143-148.
[12]	DAI J Y, MA S Q, WU Y G , et al. High bio-based content waterborne UV-curable coatings with excellent adhesion and flexibility[J]. Progress in Organic Coatings, 2015,87:197-203.
[13]	LIU J C, LIU R, ZHANG X P , et al. Preparation and properties of UV-curable multi-arms cardanol-based acrylates[J]. Progress in Organic Coatings, 2016,90:126-131.
[14]	DAI J Y, MA S Q, ZHU L X , et al. UV-thermal dual cured anti-bacterial thiol-ene networks with superior performance from renewable resources[J]. Polymer, 2017,108:215-222.

[1]	LI M Y, WEI D D, GE X Y, et al. Preparation and Performance of UV-curable Epoxidized Soybean Oil-based Polyurethane Acrylate Coatings [J]. Paint & Coatings Industry, 2025, 55(7): 46-51.
[2]	FAN X H, NIE J Q, LI H H, et al. Research on Thioalcohol-click Modification of PVAc-based Core/shell Emulsion and Its Rapid Film Forming Performance [J]. Paint & Coatings Industry, 2025, 55(1): 15-.
[3]	LI H Z, WEI D d, ZENG J J, et al. Preparation of Castor Oil-based Photosensitive Resin and Performance of Its UV-LED Shadowless Adhesives [J]. Paint & Coatings Industry, 2024, 54(5): 14-19.
[4]	LIU Y P, ZHANG G H, DU J N, et al. Preparation and performance study of gallic acid esters/modified styrene-acrylic anticorrosive rust conversion latex [J]. Paint & Coatings Industry, 2024, 54(10): 45-52.
[5]	ZHANG Z J, PAN W H, LIU R, et al. Preparation and Anti-corrosion Properties of Photocurable Coating with Photosensitive Phosphate-doped Polyaniline [J]. Paint & Coatings Industry, 2023, 53(7): 1-12.
[6]	Hu Yaqi, Hu Yunyong, Fu Changqing, Shen Liang,. Preparation and Performance of Rapeseed Oil-Based UV-Curable Coatings Film [J]. Paint & Coatings Industry, 2019, 49(6): 15-18.
[7]	Wang Changkun, Liang Liang, Pu Yongxiang, Wang Songqing. Synthesis and Application of Solvent-free Castor Oil Polyester Polyol [J]. Paint & Coatings Industry, 2019, 49(3): 14-19.
[8]	Yanfei Feng,Ziping Pan. Research Progress of Rust Converter in Waterborne Anticorrosion Coatings [J]. Paint & Coatings Industry, 2018, 48(8): 49-54.
[9]	Hongjing Ding,Changqing Fu,Liang Shen. Study on Water Whitening of Castor Oil-Based Polyurethane-Acrylate Composite Film [J]. Paint & Coatings Industry, 2018, 48(5): 14-19.
[10]	Shuili Lai,Chen Gao,Zhuan Liu,Ruiqi Wang. Preparation of Crosslinked Waterborne Polyurethane from Castor Oil Modified by Maleic Anhydride [J]. Paint & Coatings Industry, 2018, 48(10): 38-42.
[11]	Peng Guixiang, Fu Changqing, Shen Liang ,. Preparation and Properties of Fully Oleic Acid-Based Waterborne Polyurethane [J]. Paint & Coatings Industry, 2016, 46(9): 14-20.
[12]	Sheng Songsong, Jiang Pingping, Zhang Pingbo, Tang Minyan, Yu Xiaoqin, Bao Yanmin. Properties of Sulfonated Waterborne Polyurethane Dispersions Modified by Castor Oil [J]. Paint & Coatings Industry, 2016, 46(6): 28-33.
[13]	Li Peng, Ma Songqi, Jiao Weizhou, Liu Xiaoqing, Zhu Jin. Research Progress in Vegetable Oil-Based UV Curable Coatings [J]. Paint & Coatings Industry, 2016, 46(5): 81-87.
[14]	Zhang Guanghua, Xu Feng. Study on Synthesis and Performance of Waterborne Rust Conversion Anticorrosive Emulsion [J]. Paint & Coatings Industry, 2016, 46(11): 51-57.
[15]	He Jinwen, Yang Qingping, Huang Shunli, Gao Jingya, Qing Ning. Preparation of Polyaspartic Ester Modified with Epoxidized Soybean Oil [J]. Paint & Coatings Industry, 2015, 45(8): 29-33.

Please choose a citation manager

Content to export

Preparation and Properties of Bio-Based Thiol-Ene UV Curing Coating

生物基巯基-烯UV固化涂膜的制备及性能研究

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

模态框（Modal）标题

Please choose a citation manager

Content to export

Preparation and Properties of Bio-Based Thiol-Ene UV Curing Coating

生物基巯基-烯UV固化涂膜的制备及性能研究

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments