Abstract: 
										
	[Objective]To prepare stabilized hydroxyacrylic emulsions with high solids and high hydroxyl content.[Methods]Using butyl acrylate(BA)and isooctyl acrylate(EHA)as soft monomers, styrene(St) and methyl methacrylate(MMA) as hard monomers,and hydroxyethyl methacrylate(HEMA)as a functional monomer,we focused on the effects of oil-to-water ratio and emulsifier dosageon the stability of the pre-emulsions through the reactive free-radical emulsion polymerization methodand further explored the effects of the proportion of hydroxyl monomer in the core-shell layer on thegelation rate of the emulsion.[Results]The emulsifier dosage was 1. 5% of the total monomer mass, and the mass ratio of anionic emulsifier to nonionic emulsifier was 2∶1. The stability of the pre-emulsion was excellent when the oil-to-water ratio was 2∶1,and no delamination was observed when it was left to stand for 24 h. When the core-to-shell mass ratio was 1∶1 and the mass ratio of hydroxyl monomer distributed in the core layer to that in the shell layer was 1∶1(a hydroxyl monomer content of approximately 32. 1% in both layers), the polymerization gel rate could be reduced to 0. 048%.[Conclusion]A hydroxy acrylic emulsion with a hydroxyl content of 4. 2% and a solid content of 45% was prepared,and the prepared paint film had a hardness of 2H,a gloss of 85. 7 at 20°,a gloss of 92. 9 at 60°,a short drying time,and good water resistance. 
									
																									Key words: 
																																						   hydroxyacrylic latex, 
																																							   high hydroxyl content, 
																																							   polyurethane paint film, 
																																							   emulsion , 
																																							   stability, 
																																							   emulsion polymerization 
																												
																								摘要: 
	【目的】制备稳定的高固含高羟基含量羟基丙烯酸乳胶。【方法】以丙烯酸丁酯( BA)、丙烯酸异辛酯(EHA)为软单体,苯乙烯( St)、甲基丙烯酸甲酯( MMA)为硬单体,甲基丙烯酸羟乙酯(HEMA)为功能单体,通过活性自由基乳液聚合法,制备了高羟基含量羟基丙烯酸乳胶,着重研究了油水比、乳化剂用量对预乳液稳定性的影响,并进一步探究了羟基单体在核壳层中占比对凝胶率的影响。【结果】乳化剂用量占单体总质量 1. 5%,阴离子乳化剂与非离子乳化剂质量比为 2∶1,油水比为 2∶1时,预乳液稳定性优异,静置 24 h不分层。核壳质量比为 1∶1,核壳中羟基单体质量比 1∶1,核壳中羟基单体质量占比均为 32. 1%时,聚合凝胶率可降至 0. 048%。【结论】成功制备了羟基含量为 4. 2%,固含量为 45%的羟基丙烯酸乳胶,所制备的漆膜硬度为 2H,20°光泽为 85. 7, 60°光泽为 92. 9,干燥时间短,耐水性好。
																								关键词: 
								   																																   羟基丙烯酸乳胶, 
																																											   高羟基含量, 
																																											   聚氨酯漆膜, 
																																											   乳液稳定性, 
																																											   乳液聚合 
																													
															
                            
                                                        	
								
								CLC Number: 
								 
								
								
								                            
                            
                            
                                
                                    
                                
                                
                                    
																				                                              LI X K, WU D, CHAI Y J. Preparation of High Hydroxyl Content Hydroxy Acrylic Latex[J]. Paint & Coatings Industry, 2025, 55(7): 8-13.
																																																					李雪坤, 巫丹, 柴延军. 高羟基含量羟基丙烯酸乳胶的制备[J]. 涂料工业, 2025, 55(7): 8-13.