Abstract:
In order to overcome the problem of poor performance of waterborne coatings on polycarbonate(PC)plastics. Methyl methacrylate(MMA),styrene(St)and butyl acrylate(BA) were used as the main monomer,itaconic acid as a functional monomer,the introduction of a long-chain alkyl monomer lauryl methacrylate(LMA) and acetoacetoxyethyl methacrylate(AAEM)/polyether amine were cross-linking system,which prepared a self-linked acrylic latex. The effects of functional monomers,itaconic acid,LMA and AAEM/polyether amine on theperformance of acrylic latex and coating film were discussed. The experimental results showed that whenthe itaconic acid was 3. 0% of the total monomers,LMA 4. 5%,AAEM 9. 0%,and AAEM/polyether amine molar ratio was 2∶1,the prepared single-group water-based acrylic coatings presented excellent adhesion,ethanol-resistant and cooking-resistant on the PC plastic.
Key words:
plastic coatings,
acrylic latex,
cooking-resistant,
ethanol-resistant,
adhesion
摘要: 为克服水性涂料在聚碳酸酯( PC)塑料上综合性能不佳的问题,以甲基丙烯酸甲酯(MMA)、苯乙烯( St)、丙烯酸丁酯( BA)为主单体,衣康酸为功能单体,引入长链烷基单体甲基丙烯酸月桂酯( LMA),以及乙酰乙酸基甲基丙烯酸乙酯( AAEM)/聚醚胺交联体系,制备了一种自交联丙烯酸乳胶,研究了不同功能单体、衣康酸、 LMA和 AAEM/聚醚胺对乳胶及涂膜性能的影响。结果表明:衣康酸用量为 3. 0%(以单体总质量计,下同)、 LMA用量为 4. 5%、AAEM用量为 9. 0%、AAEM与聚醚胺物质的量比为 2∶1时,制备的单组分水性丙烯酸涂料在 PC塑料上具有优异的附着力、耐乙醇擦拭性和耐蒸煮性。
关键词:
塑料涂料,
丙烯酸乳胶,
耐蒸煮性,
耐乙醇擦拭性,
附着力
CLC Number:
JIA B, CAO J S, QIAO Y L, et al. The Preparation and Research of Acrylate Latex Based on Polycarbonate Highly Resistant Plastic Paint[J]. Paint & Coatings Industry, 2024, 54(5): 27-31.
贾斌, 曹劲松, 乔永洛, 等. 基于聚碳酸酯高耐性塑料涂料用丙烯酸乳胶的制备与研究[J]. 涂料工业, 2024, 54(5): 27-31.