摘要： 采用可再生资源环氧大豆油（ESBO）作为原料与二氧化碳反应合成环碳酸酯基大豆油（CSBO），再通过 CSBO与乙二胺及二乙烯三胺分别反应制备非异氰酸酯聚氨酯（NIPU）预聚体；以其作为固化剂与环氧树脂 E-51反应制备环氧 －非异氰酸酯聚氨酯杂化涂膜。通过 FT-IR对 NIPU预聚物结构进行分析，证明了聚氨酯特征基团氨基甲酸酯键的生成；所制备的清漆涂膜综合性能优良，对比纯环氧体系，其耐化学性、耐磨性能更优异；同时其制备过程中不使用有毒性的异氰酸酯，安全环保。

关键词: 可再生资源, 非异氰酸酯聚氨酯, 杂化涂料

Abstract: The cyclic carbonate soybean oil( CSBO )was prepared by using the renewable resources soybean oil and carbon dioxide, then the non- isocyanate polyurethane(NIPU)prepolymer with the amino was systhesised by the reaction between the CSBO and the ethylene diamine and diethylene triamine respectively. The epoxy -NIPU hybrid coating was prepared by using NIPU as the curing agent and epoxy resin. The formation of urethanes group, the char-acteristic group of PU, was verified by FT-IR analysis. The hybrid coating showed high pertormance, especially the excellent chemical resistance and wear resistance. The preparation process was safe and environment frendily, as no use of the toxic isocyanate.

Key words: renewable resources, non-isocyanate polyurethane, hybrid coating