摘要： 概述了原子转移自由基聚合(ATRP)技术实施中存在的包括溶剂化效应、季铵化反应和氧化还原反应等副反应及对产物可控性的主要影响。
关键词:
ATRP,
副反应,
溶剂效应,
季铵化
Abstract: Significant side reactions associated in the atom transfer radical polymerization (ATRP ) are reviewed. Particular emphasis was placed on solution effect, quaterisation and redox reaction in their influence on the controllability of end products.
Key words:
ATRP,
side reaction,
solvent effect,
quaterisation
熊邦虎, 郑仕远, 田骏翔. 副反应对原子转移自由基聚合技术定制聚合物的影响[J]. 涂料工业, 2010, 40(11): 76-79.
Xiong Banghu, Zhen Shiyuan, Tian Junxiang. Influence of Side Reaction on the Tailored Polymers via Atom Transfer Radical Polymerization(ATRP)[J]. Paint & Coatings Industry, 2010, 40(11): 76-79.