Study on Flame Retardant Property of Nano Zinc/Sodium Sulfide/Epoxy Acrylate Coatings

doi:10.12020/j.issn.0253-4312.2018.12.1

Paint & Coatings Industry ›› 2018, Vol. 48 ›› Issue (12): 1-6. doi: 10.12020/j.issn.0253-4312.2018.12.1

• Research & Development • Next Articles

Study on Flame Retardant Property of Nano Zinc/Sodium Sulfide/Epoxy Acrylate Coatings

Xiaodan Huang,Ning Wang,Mingzhen Huang,Zhenhui Wang,Lei Yang,Bingyun Zheng

College of Environmental and Biological Engineering,Fujian Provincial Key Laboratory of Ecology-Toxicological Effects & Control for Emerging Contaminants,Putian University, Putian, Fujian, 351100,China

Received:2018-09-13 Online:2018-12-01 Published:2018-12-20
Contact: Bingyun Zheng

纳米锌/硫化钠/环氧丙烯酸酯涂层的阻燃性能研究

黄晓丹,王宁,黄明真,王振辉,杨磊,郑炳云

莆田学院环境与生物工程学院,福建省新型污染物生态毒理效应与控制重点实验室,福建莆田 351100

通讯作者: 郑炳云
作者简介:黄晓丹(1978—),女,副教授,主要从事纳米材料制备及功能高分子材料研究。
基金资助:
福建省高校产学合作项(2015H61010065);莆田市科技计划项目(2015G2012);福建省自然科学基金项目(2017J01710);福建省教育厅项目(JAT160447);莆田学院项目(2016035);莆田学院功能材料研究创新团队项目([莆院科[2014]8号]);大学生创新创业训练计划项目(201611498031);大学生创新创业训练计划项目(201711498005);大学生创新创业训练计划项目(201611498030)

Abstract

Abstract:

To study the flame retardant effect of nano-zinc and sodium sulfide on epoxy acrylate (EA) coatings, a nano-zinc was prepared by plant reduction method using zinc acetate and alfalfa powder as raw materials. Then a nano zinc/sodium sulfide/EA flame retardant coating was prepared by mixing nano-zinc, sodium sulfide into EA and UV-curing method. Some properties such as flame retardancy, light transmittance, thermal stability and hardness of the coating were measured by Fourier infrared spectrometer, ultraviolet visible spectrophotometer, differential scanning calorimetry and mechanical analyzer. The results showed the nano-zinc/sodium sulfide/EA coating had the best flame retardancy when the mass content of nano-zinc was 10%, and its residual carbon yield and limit oxygen index reached 19.47% and 31 respectively. The hardness of all flame retardant coatings was 6 H. The thermal stability of the coatings increased with the increase of nano zinc content while the transmittance decreased gradually.

Key words: plant reduction method, nano zinc, epoxy acrylate coatings, flame retardant, thermal stability

摘要：

为探讨纳米锌与硫化钠对环氧丙烯酸酯(EA)涂层的阻燃效果,以乙酸锌和苜蓿粉为原料,利用植物还原法制备了纳米锌,将其与硫化钠及EA配合,经紫外光固化制备纳米锌/硫化钠/EA阻燃涂层。通过红外、紫外、差示扫描量热仪及力学分析仪对其阻燃、透光率、热稳定性及硬度等性能进行测定。结果表明:当纳米锌质量分数为10%时,纳米锌/硫化钠/EA涂层阻燃性能最佳,涂层残余率达19.47 %,极限氧指数达31。所有涂层硬度均为6H,涂层热稳定性随纳米锌质量分数的增加而增加,而透光率逐渐下降。

关键词: 植物还原法, 纳米锌, 环氧丙烯酸酯涂层, 阻燃, 热稳定性

CLC Number:

TQ630.7

Xiaodan Huang,Ning Wang,Mingzhen Huang,Zhenhui Wang,Lei Yang,Bingyun Zheng. Study on Flame Retardant Property of Nano Zinc/Sodium Sulfide/Epoxy Acrylate Coatings[J]. Paint & Coatings Industry, 2018, 48(12): 1-6.

黄晓丹,王宁,黄明真,王振辉,杨磊,郑炳云. 纳米锌/硫化钠/环氧丙烯酸酯涂层的阻燃性能研究[J]. 涂料工业, 2018, 48(12): 1-6.

/ / Recommend / Download Citations

URL: https://www.cn-pci.com/EN/10.12020/j.issn.0253-4312.2018.12.1

https://www.cn-pci.com/EN/Y2018/V48/I12/1

References

[1]	YANG L, XU Z H, WANG X H . Synergistic effects of organically modified montmorillonite on the flame-retardant and smoke suppression properties of transparent intumescent fire-retardant coatings[J]. Progress in Organic Coatings, 2018,122:107-118.
[2]	WEN P Y, WANG X F, FENG X M , et al. A novel UV-curing flame retardant film with significantly intumescent effect[J]. Polymer Degradation and Stability, 2015,119:288-294.
[3]	LIANG S Y, NEISIUS M N, GAAN S . Recent developments in flame retardant polymeric coatings[J]. Progress in Organic Coatings, 2013,76(11):1642-1665.
[4]	CHEN L J, SONG L, LI P , et al. A new intumescent flame retardant containing phosphorus and nitrogen: preparation, thermal properties and application to UV curable coating[J]. Progress in Organic Coatings, 2011,70(1):59-66.
[5]	XING W Y, HU Y, SONG L , et al. Thermal degradation and combustion of a novel UV curable coating containing phosphorus[J]. Polymer Degradation and Stability, 2009,94:1176-1182.
[6]	CHEN X L, HU Y, JIAO C M , et al. Preparation and thermal properties of a novel flame-retardant coating[J]. Polymer Degradation and Stability, 2007,92:1141-1150.
[7]	KARATAŞ S, HOŞGÖR Z, KAYAMAN-APOHAN N , et al. Preparation and characterization of phosphine oxide containing organosilica hybrid coatings by photopolymerization and sol-gel process[J]. Progress in Organic Coatings, 2009,65:49-55.
[8]	TANG T, CHEN X C, MENG X Y , et al. Synjournal of multiwalled carbon nanotubes by catalytic combustion of polypropylene[J]. Angewandte Chemie International Edition, 2005,44(10):1517-1520.
[9]	陈业中, 管会彬, 彭华乔 , 等. 新型含磷氮硫阻燃剂的合成及其在聚氨酯中的应用[J]. 塑料工业, 2013: 41(5):116-119.
[10]	PARK S J, JIN F L . Synjournal and characterization of UV-curable acrylic resin containing fluorine groups[J]. Polymer International, 2005,54(4):705-709.
[11]	CANIZAL G, SCHABES P S, PAL U , et al. Controlled synjournal of Zn ⁰ nanoparticles by bioreduction [J]. Materials Chemistry and Physics, 2006,97(2):321-329.
[12]	WANG X F, WANG B B, XING W Y , et al. Flame retardancy and thermal property of novel UV-curable epoxy acrylate coatings modified by melamine-based hyperbranched polyphosphonate acrylate[J]. Progress in Organic Coatings, 2014,77(1):94-100.
[13]	WANG P, CHEN Y, ZHAO F X , et al. Preparation of Nano-zinc Powders by DC Arc Plasma Evaporation Method and Its Mechanism[J]. Foundry Technology, 2012,33(05):531-533.
[14]	SENAPATIA U S, SARKAR D . Synjournal and characterization of biopolymer protected zinc sulphide nanoparticles[J]. Superlattices and Microstructures, 2015,85:722-733.
[15]	XING W Y, JIE G X, SONG L , et al. Flame retardancy and thermal properties of epoxy acrylate resin/alpha-zirconium phosphate nanocomposites used for UV-curing flame retardant films[J]. Materials Chemistry and Physics, 2011,125(1-2):196-201.
[16]	WANG D, MU X W, CAI W , et al. Constructing phosphorus, nitrogen, silicon-co-contained boron nitride nanosheets to reinforce flame retardant properties of unsaturated polyester resin[J]. Composites Part A: Applied Science and Manufacturing, 2018,109:546-554.
[17]	CAKMAKCL E . Allylamino diphenylphosphine oxide and poss containing flame retardant photocured hybrid coatings[J]. Progress in Organic Coatings, 2017,105:37-47.

Please choose a citation manager

Content to export

Study on Flame Retardant Property of Nano Zinc/Sodium Sulfide/Epoxy Acrylate Coatings

纳米锌/硫化钠/环氧丙烯酸酯涂层的阻燃性能研究

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	FANG J J, WANG Q H, XU K, et al. The Current Situation and Research Progress of Fireproof Coatings in the Oil and Gas Field [J]. Paint & Coatings Industry, 2025, 55(8): 75-82.
[2]	WANG W S. Academic Research on Waterborne Polyurethane Coatings in the Past 5 Years [J]. Paint & Coatings Industry, 2024, 54(增刊1): 6-13.
[3]	JIA H, SUN J, ZHANG X L, et al. Preparation and Performance Study of High Efficient Phosphorus-nitrogen-silicon Fire Retardtant Coating [J]. Paint & Coatings Industry, 2024, 54(3): 2-7.
[4]	GAO M, LÜ C, WANG P, et al. Study on Polyurethane-based Expansion Materials Modified by Deactivated Flame Retardant Polyurea Coating [J]. Paint & Coatings Industry, 2024, 54(12): 2-9.
[5]	SUN K, OU Y, LI H Y, et al. Development of Flame Retardant Protective Coatings for High Adhesion Lightweight Composite Materials [J]. Paint & Coatings Industry, 2024, 54(11): 30-35.
[6]	LI A M, LIUH Z, QU Z C. Preparation of Boron Nitride Based Thermal Conductive Flame Retardant Waterborne Coatings [J]. Paint & Coatings Industry, 2024, 54(11): 57-62.
[7]	ZHENG B Y, CHEN Z X, FU M L, et al. Preparation and Performance Characterization for Flame Retardant Coating of Nano-SiO2/C60/Epoxy Resin [J]. Paint & Coatings Industry, 2023, 53(8): 14-19.
[8]	Liu Qi, Qin Jiaxin, Wang Cheng, Chen Zihui,. The Development and Application of Ceramic Composite Coatings for Glass Fiber Reinforced Plastics [J]. Paint & Coatings Industry, 2020, 50(8): 52-56.
[9]	Feng Qin, Feng Jun, Ye Daiyong. Study on Waterborne UV-Curable Polyurethane Acrylate Clearcoat and Its performance Based on Nano ZnO as Photoinitiator [J]. Paint & Coatings Industry, 2019, 49(7): 1-7.
[10]	Han Chao, Dong Xiang, Xing Shichao, Jin Die, Kong Fanbei, Nie Shibin. Study on Flame Retardancy and Smoke Suppression of Transparent Intumescent Flame Retardant Coatings [J]. Paint & Coatings Industry, 2019, 49(7): 16-20.
[11]	Yang Lei, Ao Huahe, Huang Mingzhen, Wang Zhenhui, Zheng Bingyun. Preparation of Polyhydroxyphosphate / Acrylate Light-cured Flame Retardant Coating [J]. Paint & Coatings Industry, 2019, 49(2): 14-21.
[12]	CHEN K, YAO B L, HU X C, et al. Preparation and Properties of Fluorine Modified UV Curing Six-Arm Flame Retardant Polyurethane [J]. Paint & Coatings Industry, 2019, 49(12): 1-8.
[13]	Zheng Bingyun, Fu Minglian Peng Libo, Yang Lei. Properties of 1-vinyl-3-alkylimidazole bromide Ionic Liquids / Epoxy Acrylate Flame Retardant Coatings [J]. Paint & Coatings Industry, 2019, 49(1): 13-17.
[14]	Jing Chen,Jianjun Yang,Jian’an Zhang,Libing Fu,Qingyun Wu,Mingyuan Wu,Lei Wang,Chaoyang Ding. Synthesis and Properties of Nano-SiO₂-Perfluoroalkyl Acrylate Modified Acrylate Emulsion via In-Situ Polymerization [J]. Paint & Coatings Industry, 2018, 48(5): 26-32.
[15]	Zhang Maowei,Zhou Hongda,Di Chunyang,Tao Gang,Liu Peili,Liu Lianhe. Effect of Different Flame Retardants on Properties of Polyurethane Damping Coatings [J]. Paint & Coatings Industry, 2018, 48(3): 69-72.

模态框（Modal）标题

Please choose a citation manager

Content to export

Study on Flame Retardant Property of Nano Zinc/Sodium Sulfide/Epoxy Acrylate Coatings

纳米锌/硫化钠/环氧丙烯酸酯涂层的阻燃性能研究

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments