Paint & Coatings Industry ›› 2023, Vol. 53 ›› Issue (12): 23-28. doi: 10.12020/j.issn.0253-4312.2023-123

• Technology • Previous Articles     Next Articles

The Effect of Fumed Silica on the Performance of Inorganic Artificial Stone Protective Coating

Liu Guangming,Liu Xiaoli,Zhao Youqiang,Wang Huaquan,Lin Yongquan,Tao Congxi   

  1. China Resources Cement Technology R&D Co.,Ltd., Guangzhou 510000,China
  • Online:2023-12-01 Published:2023-12-01

气相二氧化硅对无机人造石防护涂层性能的影响

刘广明,刘晓丽 *,赵有强,王华权,林永权,陶从喜   

  1. 华润水泥技术研发有限公司,广州 510000

Abstract: To improve the antifouling and wear-resistance of cement-based inorganicartificial stone protective coating,inorganic artificial stone anti-fouling coating was preparedusing organic silicone resin as the film-forming material and fumed silica as filler. The impactof fumed silica on the anti-fouling and wear-resistance of the coating was evaluated throughpollution of typical contaminated fluid,water contact angle,wear-resistance test and scanningelectron microscopy. The results indicated that the addition of fumed silica could effectivelyimprove the hardness and wear-resistance of the coating. However,due to its irregular surface morphology and the presence of a large number of hydroxyl groups,the surface wettability wasenhanced and the anti-fouling performance decreased at high doping level. When 3% fumed silica was added,the coating showed the best comprehensive performance,the color difference ΔE<1. 5 for methyl violet and vinegar was obtained,and a good appearance and good anti-fouling performance maintained after 4 000 times of heavy friction. This coating can be widelyused in inorganic artificial stones and other cement-based decorative materials to solve thefouling problem.


Key words: antifouling coating;inorganic artificial stone;antifouling performance;wear 

摘要: 为提高水泥基无机人造石防护涂层的耐沾污性和耐磨性,采用有机硅树脂为成膜物质,气相二氧化硅为填料,制备了无机人造石耐沾污涂层,通过典型污染液污染、水接触角和耐磨性测试及扫描电镜分析,评估了气相二氧化硅用量对涂层耐沾污性和耐磨性的影响。结果表明:气相二氧化硅的加入可以有效提高涂层的硬度和耐磨性,但由于其表面的不规则形貌和大量羟基的存在,导致其在较高的掺量下涂层表面润湿性增强且耐沾污性下降。当气相二氧化硅用量在 3%时,耐沾污涂层的综合性能最好,对甲紫和食醋污染液的色差ΔE<1. 5,负载 1 kg摩擦 4 000次仍可以保持完好外观和良好的耐沾污性。该涂层可以应用于无机人造石及其他水泥基装饰材料,解决水泥基装饰面材不耐沾污的问题。

关键词: 耐沾污涂层, 无机人造石, 耐沾污性, 耐磨性, 气相二氧化硅

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