涂料工业 ›› 2009, Vol. 39 ›› Issue (6): 1-5.

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聚丙烯酸酯结构对防火涂料防火性能的影响

许乾慰1,2,陆 彬,王国建1,2,赵 就   

  1. 1、先进土木工程材料教育部重点实验室,上海 200092;2、同济大学材料科学与工程学院,上海 200092
  • 出版日期:2009-06-01 发布日期:2019-05-30
  • 作者简介:许乾慰(1960—),男,教授,博士生导师,主要研究方向为高分子功能材料。
  • 基金资助:
    国家高新技术研究发展计划(863计划)项目,编号:2006AA03Z463

Influence of Structures of Polyacrylate Latex on the Fire-Retardant Properties of Fire-Retardant Coatings

Xu Qianwer 1,2, Lu Bin2, Wang Guojian1,2. Zhao Jiu2   

  1. 1.Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education Shanghai 200092, China;2.School of Materials Science and Engineering, Tongji University, Shanghai 200092,China
  • Online:2009-06-01 Published:2019-05-30

摘要: 研究了防火涂料基料树脂聚丙烯酸酯玻璃化转变温度、相对分子质量、乳胶粒径与炭化层结构以及防火性能之间的联系。研究结果表明,基质树脂玻璃化转变温度越低,乳胶粒子的平均粒径越小,防火涂料的耐火性能就越好;选用相对分子质量 6.8万左右的基料树脂能得到泡孔分布均匀、整体强度较好的炭化层结构,并且防火涂料耐火性能也较好。

关键词: 水性膨胀型防火涂料, 聚丙烯酸酯, 炭化层结构, 防火性能

Abstract: The relationships between the glass transition temperature, molecular weight and particle diameter of the resin binder of polyacrylate latex, structures of the carbonized layers and the fire-retardant properties were studied. Results showed that with the decrease of the glass transition temperature and the size of the latex particles of the resin binder, the fire-retardant properties were improved.Additionally,when the molecular weight was about 68 000, a carbonized layer with well-distribute inner bubbles and high overall strength was formed. and the fire-retardant properties were also good.

Key words: waterborne intumescent fire-retardant coating, polyacrylate, structure of carbonized lay-er, fire-retardant property