摘要: 为了提高聚氨酯水泥防水涂料的耐候性,在优化聚氨酯水泥防水涂料配方基础上引入 TiO2作为功能性添加剂,研制了新型的高耐候聚氨酯/TiO2-水泥复合防水涂料,探究了 TiO2添加量对涂层耐候性和吸水率等的影响。通过扫描电子显微镜对聚氨酯/TiO2-水泥复合防水涂层微观形貌进行表征,并系统测试了涂层经过紫外线、碱溶液、高温处理前后的拉伸性能以及涂层的低温柔性、不透水性、吸水率等。结果表明:聚氨酯/TiO2-水泥复合防水涂料各项性能满足 GB/T 23445—2009要求,当 TiO2质量分数为 0. 4%时,聚氨酯/TiO2-水泥复合防水涂料表现出最佳的耐紫外老化性,拉伸强度保持率达 117. 7%,断裂伸长率保持率为 76. 2%,同时还展现出良好的耐碱老化性、耐热老化性、低温柔性、不透水性以及低吸水率。制备的聚氨酯/TiO2-水泥复合防水涂料相较聚氨酯水泥防水涂料,耐候性提升,在户外防水领域具有潜在的应用前景。
关键词:
聚氨酯水泥防水涂料,
聚氨酯/TiO2-水泥复合防水涂料,
TiO2,
耐候性
Abstract: On the basis of optimized formulation of polyurethane cement waterproof coating,TiO2 was added to develop a new type of high weather resistance polyurethane/TiO2-cement composite waterproof coatings. The coating surface morphology was characterized byscanning electron microscope,the water absorption rate was tested and tensile strength before and after treatment of UV,alkali solution,and high-temperature were measured. The resultsshowed that the properties of the composite waterproof coatings met the requirements of theGB/T 23445—2009 standard. When the mass fraction of TiO2 was 0. 4%,the composite waterproof coating exhibited the best UV aging resistance(tensile strength retention rate of 117. 7% and the elongation retention rate at the break of 76. 2%),good alkali aging resistance and heat aging resistance,and lower water absorbing rate.
Key words:
polyurethane cement waterproof coatings,
polyurethane/TiO2-cement composite waterproof coatings,
TiO2,
weather resistance
中图分类号:
崔灿, 韩光明, 刘倩, 等. 高耐候聚氨酯/TiO2-水泥复合防水涂料的制备及性能研究[J]. 涂料工业, 2025, 55(4): 54-59.
CUI C, HAN G M, LIU Q, et al. Preparation and Properties of High Weather Resistance Polyurethane/TiO2-cement Composite Waterproof Coatings[J]. Paint & Coatings Industry, 2025, 55(4): 54-59.