石墨烯在防腐涂料中的应用进展

doi:10.12020/j.issn.0253-4312.2019.6.77

摘要/Abstract

摘要： 石墨烯对气体和液体完全不透过的性质，使它成为优秀的单原子厚金属保护薄膜。本文介绍了石墨烯的结构和性质优势及防腐机制，总结了近年来石墨烯防腐薄膜制备方法以及石墨烯作为填料在聚合物防腐涂层的研究概况。在此基础上详细讨论了石墨烯在防腐方面存在的问题，包括石墨烯薄膜在制备过程中容易出现缺陷问题，石墨烯不能在有机聚合物中分散均匀以及在涂层发生破坏时局部微电流腐蚀的产生等，并针对以上问题提出了相应的解决方案。最后展望了石墨烯在防腐领域中的发展方向。

关键词: 石墨烯, 防腐涂料, 薄膜缺陷, 分散, 微电流

Abstract: Graphene could be used as an excellent monoatomic thick protective film formetal owing to its impermeability to gases and liquids. The advantages of structures andproperties of graphene and its anti-corrosion mechanism were described in this article，also presented were the preparation of graphene protective film and study on uses as a filler in anti-corrosive coatings.On this basis，the application problems of graphene in corrosion protection was discussed in detail，including defect formation in graphene film preparation process，the difficulty of dispersion of graphene in organic polymers，and local micro-current corrosion occurred in the broken coatings layer. Various corresponding measures were proposed to solvethese problems. Finally，the development trend of graphene in the field of corrosion protection was prospected.

Key words: graphene, anti-corrosion coatings, film defect, dispersion, micro-current

中图分类号:

TQ635.2

张海永, 吕心顶, 郑言贞. 石墨烯在防腐涂料中的应用进展[J]. 涂料工业, 2019, 49(6): 77-81.

Zhang Haiyong, Lv Xinding, Zheng Yanzhen. Progress in Application of Graphene in Corrosion Protective Coatings[J]. Paint & Coatings Industry, 2019, 49(6): 77-81.

https://www.cn-pci.com/CN/Y2019/V49/I6/77

参考文献

[1]XUY，YAN J，SUN F，et al. Effect of alloyed Al on the cor. rosion behaviour of ni -base alloys in molten glass understatic condition[J].[J].Corrosion Science, 2016, 112:635-646
[2]孔祥千，冯义成，张靖，等.含量对 ---合金腐蚀性能的影响[J].腐蚀科学与防护技术, 2018, 30(2):157-162
[3]BELLEZZE T，ROVENTI G，FRATESI R.Electrochemical characterization of three corrosion-resistant alloys after processing for heating-element sheathing[J].ElectrochimicaActa, 2004, 49(17-18):3005-3014
[4]LIS，FU J.Improvement in corrosion protection propertiesof TiO2，coatings by chromium doping[J].Corrosion Science, 2013, 68(1):101-110
[5]YUNH，LI J，CHEN H B，et al.A study on the N-，S-and Cl-modified nano-TiO2，coatings for corrosion protection ofstainless steel[J].Electrochimica Acta, 2007, 52(24):6679-6685
[6]KARTSONAKIS I A，BALASKAS A C，KOUMOULOS E P， et al.Incorporation of ceramic nanocontainers into epoxycoatings for the corrosion protection of hot dip galvanizedsteel[J].Corrosion Science, 2012, 57(2):30-41
[7]MOSTAFAEI A，NASIRPOURI F.Epoxypolyaniline-ZnOnanorods hybrid nanocomposite coatings：synthesis，characterization and corrosion protection performance of conduct.ing paints[J].Progress in Organic Coatings, 2014, 77(1):146-159
[8]ZHANGY，SHAO Y，LIU X，et al. A study on corrosion pro.tection of different polyaniline coatings for mild steel[J].[J].Progress in Organic Coatings, 2017, 111:240-247
[9]WEIH，WANG Y，GUO J，et al.Advanced micronanocapsules for self-healing smart anticorrosion coatings[J].Jour.nal of Materials Chemistry A, 2015, 3(2):469-480
[10]OKAFOR P C，LIU X，ZHENG Y G.Corrosion inhibition of mild steel by ethylamino imidazoline derivative in CO-saturated solution[J].Corrosion Science, 2009, 51(4):761-768
[11]XU B，GONG W，ZHANG K，et al. Theoretical predictionand experimental study of 1-butyl-2 - benzimidazole as a novel corrosion inhibitor for mild steel in hydrochloric acid[J].[J].Journal of the Taiwan Institute ofChemical Engineers, 2015, 51:193-200
[12]PRABAKARAN M，KIM S H，HEMAPRIYA V，et al.Rhus verniciflua as a green corrosion inhibitor for mild steel in 1M H2SO4[J].RSC Advances, 2016, 6(62):57144-57153
[13]B.HM SGraphene against corrosion[J].Nature Nanotech.nology, 2014, 9(10):741-
[14]NETOAHC，GUINEA F，PERES N M R，et al.The electronic properties of graphene[J].Reviews of Modern Physics, 2009, 81(1):109-114
[15]LEE C，WEI X，KYSAR J W，et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science, 2008, 321(5887):385-388
[16]CUI Y，KUNDALWAL S I，KUMAR S. Gas barrier perfor.mance of graphene polymer nanocomposites[J].[J].Carbon, 2016, 98:313-333
[17]STOLLER M D，PARK S，ZHU Y，et al.Graphene-based ultracapacitors[J].Nano Letters, 2008, 8(10):3498-3502
[18]SHIU S C，TSAI J L.Characterizing thermal and mechanical properties of grapheneepoxy nanocomposites[J].Com.posites Part B Engineering, 2014, 56(1):691-697
[19]GIRDTHEP S，SANKONG W，PONGMALEE A，et al. En. hanced crystallization，thermal properties，and hydrolysis re. sistance of polyand its stereocomplex by in.corporation of graphene nanoplatelets[J].[J].Polymer Testing, 2017, 61:229-239
[20]JI X，XU Y，ZHANG W，et al. Review of functionalization， structure and properties of graphenepolymer composite fi.bers[J].[J].Composites Part A, 2016, 87:29-45
[21]ANWAR Z，KAUSAR A，RAFIQUE I，et al.Advances in epoxygraphene nanoplatelet composite with enhanced physical properties：a review[J].Polymer-Plastics Technology and Engineering, 2016, 55(6):643-662
[22]YOONESSI M，SHI Y，SCHEIMAN D A，et al.Graphene polyimide nanocomposites；thermal，mechanical，and high-temperature shape memory effects[J].ACS Nano, 2012, 6(9):7644-7655
[23]KANDANUR S S，RAFIEE M A，YAVARI F，et al.Suppression of wear in graphene polymer composites[J].Carbon, 2012, 50(9):3178-3183
[24]LI Y，WANG Q，WANG T，et al.Preparation and tribological properties of graphene oxidenitrile rubber nanocompos.ites[J].Journal of Materials Science, 2012, 47(2):730-738
[25]PADENKO E，ROOYEN L V，WETZEL B，et al.quot;Ultralow" sliding wear polytetrafluoro ethylene nanocomposites withfunctionalized graphene[J].Journal of Reinforced Plastics &Composites, 2016, 35(11):892-901
[26]NOVOSELOV K S，FAL' KO V I，COLOMBO L，et al.A roadmap for graphene[J].Nature, 2012, 490(7419):192-200
[27]WUZS，REN W，GAO L，et al.Synthesis of graphenesheets with high electrical conductivity and good thermalstability by hydrogen arc discharge exfoliation[J].ACS Na.no, 2009, 3(2):411-417
[28]OBRAZTSOV A N，TYURNINA A V，OBRAZTSOVA E A， et al.Raman scattering characterization of CVD graphitefilms[J].Carbon, 2008, 46(6):963-968
[29]CHEN S，BROWN L，LEVENDORF M，et al.Oxidation resistance of graphene-coated Cu and CuNi alloy[J].ACS Na.no, 2010, 5(2):1321-1327
[30]YU F，CAMILLI L，WANG T，et al. Complete long-term cor.rosion protection with chemical vapor deposited graphene[J].[J].Carbon, 2018, 132:78-84
[31]QUEZADA-RENTERíA J A，CHáZARO-RUIZ L F，RAN. GEL-MENDEZ J R. Synthesis of reduced graphene oxidefilms onto carbon steel by cathodic electrophoreticdeposition：anticorrosive coating[J].[J].Carbon, 2017, 122:266-275
[32]KANG D，KWON J Y，CHO H，et al.Oxidation resistance of iron and copper foils coated with reduced graphene oxidemultilayers[J].ACS Nano, 2012, 6(9):7763-7769
[33]LI Y，YANG Z，QIU H，et al.Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coat.ings[J].Journal of Materials Chemistry A, 2014, 2(34):14139-14145
[34]CHEN C，HE Y，XIAO G，et al.Two-dimensional hybrid materials：MoS2-rGO nanocomposites enhanced the barrierproperties of epoxy coating[J].Applied Surface Science, 2018, 444(30):511-521
[35]SCHRIVER M，REGAN W，GANNETT W J，et al.Graphene as a long -term metal oxidation barrier：worse than nothing[J].ACS Nano, 2013, 7(7):5763-5768
[36]HSIEH Y P，HOFMANN M，CHANG K W，et al.Completecorrosion inhibition through graphene defect passivation[J].ACS Nano, 2014, 8(1):443-448
[37]ZHOU F，LI Z，SHENOY G J，et al.Enhanced room-temperature corrosion of copper in the presence of graphene[J].ACS Nano, 2013, 7(8):6939-6947
[38] CUI C，LIM A T O，HUANG J.A cautionary note on gra. phene anti -corrosion coatings[J]. Nature Nanotechnology， 2017，12（9）834-835.
[39]ANISUR M RANERJEE P C，EASTON C D，et al. Con. trolling hydrogen environment and cooling during CVD graphene growth on nickel for improved corrosion resistance[J].[J].Carbon, 2018, 127:131-140
[40] CHANG K C，LU H I，LAI M C，et al.Enhancement of phys.ical properties of electroactive polyimide nanocompositesby addition of graphene nanosheets[J]. Polymer Internation.al，2014，63（6）1011-1017.
[41]ZHAO Y，MA JHEN K，et al.One-pot preparation of graphene-based polyaniline conductive nanocomposites for an.ticorrosion coatings[J].Nano, 2017, 12(5):1750056-
[42]HAGHDADEH P，GHAFFARI M，RAMEZANZADEH B，et al. The role of functionalized graphene oxide on the mechanicaland anti-corrosion properties of polyurethane coating[J].[J].Journal of the Taiwan Institute of Chemical Engineers, 2018, 86:199-212
[43]RAMEZANZADEH B，NIROUMANDRAD S，AHMADI A， et al. Enhancement of barrier and corrosion protection per.formance of an epoxy coating through wet transfer of aminofunctionalized graphene oxide[J].[J].Corrosion Science, 2016, 103:283-304
[44]QIU S，LI W，ZHENG W，et al.Synergistic effect of polypyrrole-intercalated graphene for enhanced corrosion protection ofaqueous coating in 3. 5% NaCl solution[J].ACS AppliedMaterials & Interfaces, 2017, 9(39):34294-34304
[45]LI X，BANDYOPADHYAY P，GUO M，et al. Enhanced gasbarrier and anticorrosion performance of boric acid inducedcross-linked polygraphene ox. ide film[J].[J].Carbon, 2018, 133:150-161
[46]SUN W，WANG L，WU T，et al.Inhibited corrosion-promotion activity of graphene encapsulated in nanosized siliconoxide[J].Journal of Materials Chemistry A, 2015, 3(32):16843-16848

选择文件类型/文献管理软件名称

选择包含的内容