Paint & Coatings Industry ›› 2024, Vol. 54 ›› Issue (6): 47-51. doi: 10.12020/j.issn.0253-4312.2023-369

• Technology • Previous Articles     Next Articles

Study on pigmentation process of C. I. Pigment Yellow 155 with solvent

LÜ Dongjun1,2,YANG Mingran1,SHAO Lijun1,SHI Guizhi1,TANG Jing1,GAO Jingjing1,DU Xuelu1,WANG Yiran1   

  1. 1. College of Chemistry and Chemical Engineering,Dezhou University,Dezhou,Shandong 253023,China; 

    2. Shandong Provincial Engineering Research Center of Organic Functional Materials and Green Low-Carbon Technology,Dezhou,Shandong 253023,China

  • Online:2024-06-01 Published:2024-06-01

C. I.颜料黄 155的溶剂法颜料化工艺研究

吕东军 1,2,杨明冉 1,邵丽君 1,史桂之 1,唐静 1,高晶晶 1,杜雪璐 1,王一冉 1   

  1. 1.德州学院化学化工学院,山东德州 253023;

    2.有机功能材料绿色低碳技术山东省工程研究中心,山东德州 253023

  • 作者简介:吕东军(1975—),男,教授,主要研究方向为精细化工、功能性染颜料。
  • 基金资助:
    泰山产业领军人才工程项目( tscx202211094);德州市重大科技创新工程项目

Abstract: In order to improve the application performance of C. I. Pigment Yellow 155,C. I. Pigment Yellow 155 crude was obtained by diazotizing 2-amino-dimethyl terephthalateand then coupling with 1,4-diacetoacetyl p-phenylenediamine. It was treated with organic solvents(DMF and NMP), as well as hydrothermal treatment. Then,C. I. Pigment Yellow 155 samples were obtained. The color performance,crystal form,thermal resistance,contact angle,and particle size were measured. The results showed that after the pigmentations withDMF and NMP,the crystallinity of C. I. Pigment Yellow 155 crude was improved,the particle size was reduced,the particle distribution was narrower,the coloring strength was up to 109. 9%,and the hydrophobicity increased.

Key words: C. I. Pigment Yellow 155, organic pigment, solvent treatment, pigmentation

摘要: 为提高 C. I.颜料黄 155的应用性能,由 2-氨基 -对苯二甲酸二甲酯经重氮化反应后再与 1,4-双乙酰乙酰对苯二胺偶合,得到 C. I.颜料黄 155粗品,分别采用有机溶剂 N,N-二甲基甲酰胺(DMF)、 N-甲基吡咯烷酮( NMP)对其进行处理以及水热处理,得到各 C. I.颜料黄 155样品。并讨论了溶剂处理对 C. I.颜料黄 155颜料的颜色、晶型、热稳定性、水接触角、粒径等性能的影响。结果表明: C. I.颜料黄 155粗品经过 DMF和 NMP颜料化后,颜料结晶度较高且粒径减小,颗粒分布变窄,溶剂处理后的 C. I.颜料黄 155着色力可达 109. 9%,疏水性增大。

关键词: C. I.颜料黄 155, 有机颜料, 溶剂处理, 颜料化

CLC Number: