Research Progress of Graphene Modified Organic Anticorrosive Coatings

doi:10.12020/j.issn.0253-4312.2018.11.72

Abstract

Abstract:

The research progress of graphene and graphene oxide in modified organic anticorrosive coatings is reviewed. The modification and dispersion of graphene and graphene oxide, functional integration of graphene and its application in organic anticorrosive coatings, and the influence of conductivity of graphene and graphene oxide on organic anticorrosive coatings are mainly introduced. At present, one of the greatest difficulties in the application of graphene modified organic anticorrosive coating in industrial applications is how to enable the graphene modified organic anti-corrosion coating an active protection function. If the thickness of the nano-oxides layer loaded on the surface of graphene is increased up to submicron level and it has the characteristics of coarse porosity and strong bonding strength, the organic anticorrosive coatings modified by nano-oxides/graphene composite will have the properties of the barrier properties and active protection.

Key words: graphene, organic anticorrosive coatings, functional integration, conductivity, functional coatings

摘要：

综述了石墨烯及氧化石墨烯在改性有机防腐涂料领域的研究现状。主要介绍了石墨烯及氧化石墨烯的改性和分散、石墨烯的功能集成及其在有机防腐涂料中的应用以及石墨烯和氧化石墨烯导电性对于有机防腐涂料的影响。目前,石墨烯有机防腐涂层在工业应用中的最大困难之一是赋予石墨烯有机防腐涂层主动保护功能。如果在工艺创新和工艺改进后,负载在石墨烯表面的纳米氧化物层增加到亚微米厚度,并具有粗孔隙率和强结合强度的特性,纳米氧化物/石墨烯复合材料改性的有机防腐涂料将同时具备优异物理屏障性能和主动防护性能。

关键词: 石墨烯, 有机防腐涂料, 功能集成, 导电性, 功能性涂料

CLC Number:

TQ635.2

Jiaying Zhang. Research Progress of Graphene Modified Organic Anticorrosive Coatings[J]. Paint & Coatings Industry, 2018, 48(11): 72-78.

张加赢. 石墨烯改性有机防腐涂料研究进展[J]. 涂料工业, 2018, 48(11): 72-78.

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URL: https://www.cn-pci.com/EN/10.12020/j.issn.0253-4312.2018.11.72

https://www.cn-pci.com/EN/Y2018/V48/I11/72

References

[1]	SU Y, KRAVETS V G, WONG S L , et al. Impermeable barrier films and protective coatings based on reduced graphene oxide[J]. Nature Communications, 2014,5:1-5.
[2]	CHANG C H, HUANG T C, PENG C W , et al. Novel anticorrosion coatings prepared from polyaniline/graphene composites[J]. Carbon, 2012,50(14):5044-5051.
[3]	CHAUDHRY A U, MITTAL V, MISHRA B . Inhibition and promotion of electrochemical reactions by graphene in organic coatings[J]. RSC Advances, 2015,5(98):80365-80368.
[4]	MO M, ZHAO W, CHEN Z , et al. Corrosion inhibition of functional graphene reinforced polyurethane nanocomposite coatings with regular textures[J]. RSC Advances, 2016,6(10):7780-7790.
[5]	MO M, ZHAO W, CHEN Z , et al. Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets[J]. RSC Advances, 2015,5(70):56486-56497.
[6]	YU Y H, LIN Y Y, LIN C H , et al. High-performance polystyrene/graphene-based nanocomposites with excellent anti-corrosion properties[J]. Polymer Chemistry, 2014,5(2):535-550.
[7]	CHANG K C, HSU M H, LU H I , et al. Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel[J]. Carbon, 2014,66:144-153.
[8]	CHRISTOPHER G, KULANDAINATHAN M A, HARICHANDRAN G . Comparative study of effect of corrosion on mild steel with waterborne polyurethane dispersion containing graphene oxide versus carbon black nanocomposites[J]. Progress in Organic Coatings, 2015,89:199-211.
[9]	KRISHNAMOORTHY K, JEYASUBRAMANIAN K, PREMANTHAN M , et al. Graphene oxide nanopaint[J]. Carbon, 2014,72:328-337.
[10]	LI Y, YANG Z, QIU H , et al. Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings[J]. Journal of Materials Chemistry A, 2014,2(34):14139-14145.
[11]	QI K, SUN Y, DUAN H , et al. A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite[J]. Corrosion Science, 2015,98:500-506.
[12]	XIA W, XUE H, WANG J , et al. Functionalized graphene serving as free radical scavenger and corrosion protection in gamma-irradiated epoxy composites[J]. Carbon, 2016,101:315-323.
[13]	SUN W, WANG L, WU T , et al. Inhibited corrosion-promotion activity of graphene encapsulated in nanosized silicon oxide[J]. Journal of Materials Chemistry A, 2015,3(32):16843-16848.
[14]	YU K, WANG M, QIAN K , et al. The synergy effect of Graphene/SiO₂ hybrid materials on reinforcing and toughening epoxy resin[J]. Fibers and Polymers, 2016,17(3):453-459.
[15]	MA Y, DI H, YU Z , et al. Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research[J]. Applied Surface Science, 2016,360:936-945.
[16]	YU Z, DI H, MA Y , et al. Preparation of graphene oxide modified by titanium dioxide to enhance the anti-corrosion performance of epoxy coatings[J]. Surface and Coatings Technology, 2015,276:471-478.
[17]	YU Z, DI H, MA Y , et al. Fabrication of grapheme oxide-alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings[J]. Applied Surface Science, 2015,351:986-996.
[18]	ZHANG Z, ZHANG W, LI D , et al. Mechanical and anticorrosive properties of graphene/epoxy resin composites coating prepared by in-situ method[J]. International Journal of Molecular Sciences, 2015,16(1):2239-2251.
[19]	HAYATGHEIB Y, RAMEZANZADEH B, KARDAR P , et al. A comparative study on fabrication of a highly effective corrosion protective system based on graphene oxide-polyaniline nanofibers/epoxy composite[J]. Corrosion Science, 2018,133:358-373.
[20]	CHANG K C, JI W F, LI C W , et al. The effect of varying carboxylic-group content in reduced graphene oxides on the anticorrosive properties of PMMA/graphene composites[J]. EXPRESS Polymer Letters, 2014,8(12):908-919.
[21]	CHANG K C, HSU C H, LU H I , et al. Advanced anticorrosive coatings prepared from electroactive polyimide/graphene nanocomposites with synergistic effects of redox catalytic capability and gas barrier properties[J]. Express Polymer Letters, 2013,8:243-255.
[22]	SUN W, WANG L, WU T , et al. Synjournal of low-electrical-conductivity graphene/pernigraniline composites and their application in corrosion protection[J]. Carbon, 2014,79:605-614.
[23]	RAMEZANZADEH B, BAHLAKEH G, MOHAMADZADEH M H , et al. Impact of size-controlled p-phenylenediamine (PPDA)-functionalized grapheme oxide nanosheets on the GO-PPDA/epoxy anti-corrosion, interfacial interactions and mechanical properties enhancement: experimental and quantum mechanics investigations[J]. Chemical Engineering Journal, 2018,335:737-755.
[24]	PARHIZKAR N, SHAHRABI T, RAMEZANZADEH B . A new approach for enhancement of the corrosion protection properties and interfacial adhesion bonds between the epoxy coating and steel substrate through surface treatment by covalently modified amino functionalized graphene oxide film[J]. Corrosion Science, 2017,123:55-75.
[25]	FAN Y, JIANG W, KAWASAKI A . Highly conductive few-layer graphene/Al₂O₃ nanocomposites with tunable charge carrier type[J]. Advanced Functional Materials, 2012,22(18):3882-3889.
[26]	CHANG K, CHEN W . L-cysteine-assisted synjournal of layered MoS₂/grapheme composites with excellent electrochemical performances for lithium ion batteries[J]. ACS Nano, 2011,5(6) 4720-4728.
[27]	SONG Z, ZHANG Y, LIU W , et al. Hydrothermal synjournal and electrochemical performance of Co₃O₄/reduced grapheme oxide nanosheet composites for supercapacitors[J]. Electrochimica Acta, 2013,112:120-126.
[28]	YU Z, LV L, MA Y , et al. Covalent modification of graphene oxide by metronidazole for reinforced anti-corrosion properties of epoxy coatings[J]. RSC Advances, 2016,6(22):18217-18226.
[29]	RAMEZANZADEH B, GHASEMI E, MAHDAVIAN M , et al. Covalently-grafted graphene oxide nanosheets to improve barrier and corrosion protection properties of polyurethane coatings[J]. Carbon, 2015,93:555-573.
[30]	RAMEZANZADEH B, NIROUMANDRAD S, AHMADI A , et al. Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide[J]. Corrosion Science, 2016,103:283-304.
[31]	GUPTA R K, MALVIYA M, VERMA C , et al. Aminoazobenzene and diaminoazobenzene functionalized graphene oxides as novel class of corrosion inhibitors for mild steel: experimental and DFT studies[J]. Material Chemistry Physics, 2017,198:360-373.
[32]	NIKPOUR B, RAMEZANZADEH B, BAHLAKEH G , et al. Synjournal of grapheme oxide nanosheets functionalized by green corrosion inhibitive compounds to fabricate a protective system[J]. Corrosion Science, 2017,127:240-259.
[33]	TAHERI N N, RAMEZANZADEH B, MAHDAVIAN M , et al. In-situ synjournal of Zn doped polyaniline on graphene oxide for inhibition of mild steel corrosion in 3.5 wt.% chloride solution[J]. Journal of Industrial and Engineering Chemistry, 2018,63:322-339.
[34]	SUN W, WANG L, WU T , et al. Inhibiting the corrosion-promotion activity of graphene[J]. Chemistry of Materials, 2015,27(7):2367-2373.
[35]	HAYATDAVOUDI H, RAHSEPAR M . A mechanistic study of the enhanced cathodic protection performance of graphene-reinforced zinc rich nanocomposite coating for corrosion protection of carbon steel substrate[J]. Journal of Alloys and Compounds, 2017,727:1148-1156.
[36]	RAMEZANZADEH B, MOGHADAM M H M, SHOHANI N , et al. Effects of highly cystalline and conductive polyaniline/graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating[J]. Chemical Engineering Journal, 2017,320:363-375.
[37]	DING R, WANG X, JIANG J , et al. Study on evolution of coating state and role of graphene in graphene-modified low-zinc waterborne epoxy anticorrosion coating by electrochemical impedance spectroscopy[J]. Journal of Materials Engineering and Performance, 2017,26(7) 3319-3335.
[38]	DING R, ZHENG Y, YU H , et al. Study of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings[J]. Journal of Alloys and Compounds, 2018,748:481-495.
[39]	BORISOVA D, AKCAKAYIRAN D, SCHENDERLEIN M , et al. Nanocontainer-based anticorrosive coatings: effect of the container size on the self-healing performance[J]. Advanced Functional Materials, 2013,23(30):3799-3812.

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