Paint & Coatings Industry ›› 2025, Vol. 55 ›› Issue (4): 54-59. doi: 10.12020/j.issn.0253-4312.2024-372

• Technology • Previous Articles     Next Articles

Preparation and Properties of High Weather Resistance Polyurethane/TiO2-cement Composite Waterproof Coatings

CUI Can,HAN Guangming,LIU Qian,LIANG Shengkang,ZHANG Qianqian   

  1. College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao,Shandong 266100,China
  • Online:2025-04-01 Published:2025-04-01

高耐候聚氨酯/TiO2-水泥复合防水涂料的制备及性能研究

崔 灿,韩光明,刘 倩,梁生康,张前前*   

  1. 中国海洋大学化学化工学院,山东青岛266100
  • 基金资助:
    山东省重大科技创新工程:海上溢油和核事故在线监测与高效应急处置技术集成应用(2021CXGC010705) 

Abstract: On the basis of optimized formulation of polyurethane cement waterproof coating,TiO2 was added to develop a new type of high weather resistance polyurethane/TiO2-cement composite waterproof coatings. The coating surface morphology was characterized byscanning electron microscope,the water absorption rate was tested and tensile strength before and after treatment of UV,alkali solution,and high-temperature were measured. The resultsshowed that the properties of the composite waterproof coatings met the requirements of theGB/T 23445—2009 standard. When the mass fraction of TiO2 was 0. 4%,the composite waterproof coating exhibited the best UV aging resistance(tensile strength retention rate of 117. 7% and the elongation retention rate at the break of 76. 2%),good alkali aging resistance and heat aging resistance,and lower water absorbing rate. 

Key words: polyurethane cement waterproof coatings, polyurethane/TiO2-cement composite waterproof coatings, TiO2, weather resistance

摘要: 为了提高聚氨酯水泥防水涂料的耐候性,在优化聚氨酯水泥防水涂料配方基础上引入 TiO2作为功能性添加剂,研制了新型的高耐候聚氨酯/TiO2-水泥复合防水涂料,探究了 TiO2添加量对涂层耐候性和吸水率等的影响。通过扫描电子显微镜对聚氨酯/TiO2-水泥复合防水涂层微观形貌进行表征,并系统测试了涂层经过紫外线、碱溶液、高温处理前后的拉伸性能以及涂层的低温柔性、不透水性、吸水率等。结果表明:聚氨酯/TiO2-水泥复合防水涂料各项性能满足 GB/T 23445—2009要求,当 TiO2质量分数为 0. 4%时,聚氨酯/TiO2-水泥复合防水涂料表现出最佳的耐紫外老化性,拉伸强度保持率达 117. 7%,断裂伸长率保持率为 76. 2%,同时还展现出良好的耐碱老化性、耐热老化性、低温柔性、不透水性以及低吸水率。制备的聚氨酯/TiO2-水泥复合防水涂料相较聚氨酯水泥防水涂料,耐候性提升,在户外防水领域具有潜在的应用前景。


关键词: 聚氨酯水泥防水涂料, 聚氨酯/TiO2-水泥复合防水涂料, TiO2, 耐候性

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