Progress in Fluorinated and Siliconated Waterborne Polyurethane

doi:10.12020/j.issn.0253-4312.2018.7.79

Abstract

Abstract:

The incorporation of organic fluorine and silicone has been proved to be an effective way to improve water resistance and oil resistance of WPU, which greatly expands its application. In this article, the progress in both fluorinated and siliconated WPU are introduced and different modification methods are compared. Finally, future perspectives of the modified WPU are discussed.

Key words: waterborne polyurethane, organic fluorine, silicone, modification

摘要：

由于强疏水性有机氟、硅的引入,解决了水性聚氨酯耐水耐油性差的问题,大大拓展了其应用领域,受到了广泛关注。本文系统地综述了近年来有机氟、硅改性水性聚氨酯的研究进展,比较了不同改性方法的优缺点,并指出了今后的发展方向。

关键词: 水性聚氨酯, 有机氟, 有机硅, 改性

CLC Number:

TQ630.4

Guikai Zheng,Ming Lu,Xiaoping Rui. Progress in Fluorinated and Siliconated Waterborne Polyurethane[J]. Paint & Coatings Industry, 2018, 48(7): 79-87.

郑桂凯,陆明,芮小平. 有机氟、硅改性水性聚氨酯的研究进展[J]. 涂料工业, 2018, 48(7): 79-87.

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https://www.cn-pci.com/EN/Y2018/V48/I7/79

References

[1]	MENG Q B, LEE S I, NAH C , et al. Preparation of waterborne polyurethanes using an amphiphilic diol for breathable waterproof textile coatings[J]. Progress in Organic Coatings, 2009,66(4):382-386.
[2]	KRóL P . Synjournal methods, chemical structures and phase structures of linear polyurethanes. Properties and applications of linear polyurethanes in polyurethane elastomers, copolymers and ionomers[J]. Progress in Materials Science, 2007,52(6):915-1015.
[3]	BARRERE M, LANDFESTER K . High molecular weight polyurethane and polymer hybrid particles in aqueous miniemulsion[J]. Macromolecules, 2003,36(14):5119-5125.
[4]	CHATTOPADHYAY D K, RAJU K V S N . Structural engineering of polyurethane coatings for high performance applications[J]. Progress in Organic Coatings, 2007,32(3):352-418.
[5]	NOBLE K L . Waterborne polyurethanes[J]. Progress in Organic Coatings, 1997,32(1-4):131-136.
[6]	SEO J W, KIM B K . Preparations and properties of waterborne polyurethane/nanosilica composites[J]. Polymer Bulletin, 2005,54(1-2):123-128.
[7]	KIM B K . Aqueous polyurethane dispersions[J]. Colloid and Polymer Science, 1996,274(7):599-611.
[8]	YEN M S, TSAI P Y . Effects of soft segments on the surface properties of polydimethylsiloxane waterborne polyurethane prepolymer blends and treated nylon fabrics[J]. Journal of Applied Polymer Science, 2010,115(6):3550-3558.
[9]	YEN M S, TSAI P Y . Effects on the structure and properties of membranes formed by blending polydimethylsiloxane polyurethane into different soft-segment waterborne polyurethanes[J]. Journal of Applied Polymer Science, 2006,102(1):210-221.
[10]	YEN M S, TSAI P Y . Study on polyethylene glycol/polydimethylsiloxane mixing soft-segment waterborne polyurethane from different mixing processes[J]. Journal of Applied Polymer Science, 2003,90(1):233-243.
[11]	YEN M S, TSAI P Y, HONG P D . The solution properties and membrane properties of polydimethylsiloxane waterborne polyurethane blended with the waterborne polyurethanes of various kinds of soft segments[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2006,279(1-3):1-9.
[12]	WU Z F, WANG H, TIAN X Y , et al. The effects of polydimethylsiloxane on transparent and hydrophobic waterborne polyurethane coatings containing polydimethylsiloxane[J]. Physical Chemistry Chemical Physical, 2014,16(14):6787-6794.
[13]	DU Y, ZHANG J S, ZHOU C . Synjournal and properties of waterborne polyurethane-based PTMG and PDMS as soft segment[J]. Polymer Bulletin, 2016,73(1):293-308.
[14]	RAHMAN M M, HASNEEN A, KIM H D , et al. Preparation and properties of polydimethylsiloxane (PDMS)/polytetramethyleneadipate glycol (PTAd)-based waterborne polyurethane adhesives: effect of PDMS molecular weight and content[J]. Journal of Applied Polymer Science, 2012,125(1):88-96.
[15]	LEE Y H, KIM E J, KIM H D . Synjournal and properties of waterborne poly(urethane urea)s containing polydimethylsiloxane[J]. Journal of Applied Polymer Science, 2011,120(1):212-219.
[16]	FEI G Q, SHEN Y D, WANG H H , et al. Effects of polydimethylsiloxane concentration on properties of polyurethane/polydimethylsiloxane hybrid dispersions[J]. Journal of Applied Polymer Science, 2006,102(6):5538-5544.
[17]	LI X Q, FEI G Q, WANG H H . Mechanical and surface properties of membranes prepared from waterborne cationic hydroxyl-terminated polydimethylsiloxane/polyurethane surfactant-free micro-emulsion[J]. Journal of Applied Polymer Science, 2006,100(1):40-46.
[18]	WANG H H, SHEN Y D, FEI G Q , et al. Micromorphology and phase behavior of cationic polyurethane segmented copolymer modified with hydroxysilane[J]. Journal of Colloid and Interface Science, 2008,324(1-2):36-41.
[19]	王武生, 潘才元, 曾俊 , 等. 交联聚氨酯水分散体的合成[J]. 高分子学报, 2000(3):319-324.
[20]	张建安, 吴明元, 吴庆云 , 等. 有机硅改性水性聚氨酯乳液的研究[J]. 安徽大学学报, 2005,29(6):75-78.
[21]	候孟华, 刘伟区, 陈精华 . 有机硅改性水性聚氨酯乳液的研制[J]. 聚氨酯工业, 2005,20(1):30-33.
[22]	JI X, WANG H Z, MA X L , et al. Progress in polydimethylsiloxane-modified waterborne polyurethanes[J]. RSC Advances, 2017,7(54):34086-34095.
[23]	余学康, 陈昕, 王武生 . 有机硅改性水性聚氨酯分散体的制备与表征[J]. 涂料工业, 2017,47(3):44-48.
[24]	BAI C Y, ZHANG X Y, DAI J B . Synjournal and characterization of PDMS modified UV-curable waterborne polyurethane dispersions for soft tact layers[J]. Progress in Organic Coatings, 2007,60(1):63-68.
[25]	GE Z, LUO Y J . Synjournal and characterization of siloxane-modified two-component waterborne polyurethane[J]. Progress in Organic Coatings, 2013,76(11):1522-1526.
[26]	宋海香, 罗运军, 罗巨涛 , 等. 聚醚硅氧烷二元醇改性水性聚氨酯的合成及性能[J]. 上海交通大学学报, 2006,40(7):1249-1252.
[27]	ZHENG G K, LU M, RUI X P . The effect of polyether functional polydimethylsiloxane on surface and thermal properties of waterborne polyurethane[J]. Applied Surface Science, 2017,399:272-281.
[28]	JEONG H Y, LEE M H, KIM B K . Surface modification of waterborne polyurethane[J]. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 2006,290(1-3):178-185.
[29]	LEE M H, JANG M K, KIM B K . Surface modification of high heat resistant UV cured polyurethane dispersions[J]. European Polymer Journal, 2007,43(10):4271-4278.
[30]	LIM C H, CHOI H S, NOH S T . Surface modification with waterborne fluorinated anionic polyurethane dispersions[J]. Journal of Applied Polymer Science, 2002,86(13):3322-3330.
[31]	KROL P, KROL B, PIELICHOWSKA K , et al. Comparison of phase structures and surface free energy values for the coatings synjournaled from linear polyurethanes and from waterborne polyurethane cationomers[J]. Colloid and Polymer Science, 2011,289(15-16):1757-1767.
[32]	KROL P, KROL B, STAGRACZYNSKI R , et al. Waterborne cationomer polyurethane coatings with improved hydrophobic properties[J]. Journal of Applied Polymer Science, 2013,127(4):2508-2519.
[33]	YOON S C, RATNER B D . Surface structure of segmented poly(ether urethanes) and poly(ether urethane ureas) with various perfluoro chain extenders. An X-ray photoelectron spectroscopic investigation[J]. Macromolecules, 1986,19(4):1068-1079.
[34]	YOON S C, RATNER B D . Surface and bulk structure of segmented poly(ether urethanes) with perfluoro chain extenders. 3. Effects of annealing, casting solvent, and casting conditions[J]. Macromolecules, 1988,21(8):2401-2404.
[35]	LIU T, PAN X M, WU Y P , et al. Synjournal and characterization of UV-curable waterborne polyurethane acrylate possessing perfluorooctanoate side-chains[J]. Journal of Polymer Research, 2012,19(2):9741-9747.
[36]	LI J P, ZHANG X Y, LIU Z , et al. Studies on waterborne polyurethanes based on new medium length fluorinated diols[J]. Journal of Fluorine Chemistry, 2015,175:12-17.
[37]	HWANG H D, KIM H J . UV-curable low surface energy fluorinated polycarbonate-based polyurethane dispersion[J]. Journal of Colloid and Interface Science, 2011,362(2):274-284.
[38]	LIM H J, LEE Y T, PARK I J , et al. Synjournal and surface property of aqueous fluorine-containing polyurethane[J]. Journal of Colloid and Interface Science, 2001,241(1):269-274.
[39]	WU X D, ROSEN R P . Development of low-VOC 2K waterborne polyurethane anti-graffiti coatings[J]. JCT CoatingsTech, 2008,5(5):66-72.
[40]	LEVINE F, SCALA J L, KOSIK W . Properties of clear polyurethane films modified with a fluoropolymer emulsion[J]. Progress in Organic Coatings, 2010,69(1):63-72.
[41]	潘学梅, 武元鹏, 邓瑾妮 , 等. 水性含氟聚氨酯的研究进展[J]. 高分子通报, 2009(2):33-41.
[42]	TANAKA H, SUZUKI Y, YOSHINO F . Synjournal and coating application of waterborne fluoroacrylic-polyurethane composite dispersions[J]. Colloids and Surfaces A: Physiochemical and Engineering Aspects, 1999,153(1-3):597-601.
[43]	SHI R, ZHANG X Y, DAI J B , et al. Synjournal of fluorinated polyurethane polyacrylate hybrid emulsion initiated by ⁶⁰Co r-ray and properties of the latex film [J]. Journal of Macromolecular Science Part A: Pure and Applied Chemistry, 2010,47(11):1104-1110.
[44]	LI G H, LI X R, SHEN Y D , et al. Effect of hydrophilic monomer on the surface properties of cationic polyurethane-fluorinated acrylate hybrid dispersions[J]. Journal of Applied Polymer Science, 2006,99(5):2721-2725.
[45]	JIANG M, ZHENG Z H, DING X B , et al. Convenient synjournal of novel fluorinated polyurethane hybrid latexes and core-shell structures via emulsion polymerization process with self-emulsification of polyurethane[J]. Colloid and Polymer Science, 2007,285(9):1049-1054.
[46]	SHIN M S, LEE Y H, RAHMAN M M , et al. Synjournal and properties of waterborne fluorinated polyurethane-acrylate using a solvent-/emulsifier-free method[J]. Polymer, 2013,54(18):4873-4882.
[47]	ZHAO Z F, LI X R, LI P Z , et al. Study on properties of waterborne fluorinated polyurethane/acrylate hybrid emulsion and films[J]. Journal of Polymer Research, 2014,21(6):460-468.
[48]	蒋蓓蓓, 杨建军, 吴庆云 , 等. 软段含离子的含氟水性聚氨酯的制备[J]. 应用化学, 2011,28(12):1364-1369.
[49]	辛华 . 阳离子水性聚氨酯及其全氟烷基丙烯酸酯改性复合乳液的制备及性能研究[D]. 西安:陕西技术大学, 2012.
[50]	LIU S G, ZHU G Q . Effects of altered reaction conditions on the synjournal of polyurethane-poly(2,2,2-trifluoroethyl methacrylate) triblock copolymer aqueous dispersion[J]. European Polymer Journal, 2007,43(9):3904-3911.
[51]	唐华, 强涛涛 . 含硅、氟水性聚氨酯的改性方法研究进展[J]. 新型化工材料, 2016,44(6):25-27.
[52]	SU T, WANG G Y, XU X D , et al. Preparation and properties of waterborne polyurethaneurea consisting of fluorinated siloxane units[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2006,44(10):3365-3373.
[53]	SU T, WANG G Y, HU C P . Preparation and properties of well-defined waterborne polyurethaneurea with fluorinated siloxane units in hard or soft segments[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2007,45(21):5005-5016.
[54]	SU T, WANG G Y, WANG S L , et al. Fluorinated siloxane-containing waterborne polyurethaneureas with excellent hemocompatibility, waterproof and mechanical properties[J]. European Polymer Journal, 2010,46(3):472-483.
[55]	郑春森, 姚伯龙, 王利魁 , 等. 含氟有机硅和环氧复合改性水性光固化聚氨酯乳液的研究[J]. 涂料工业, 2016,46(9):39-46.
[56]	包天宇, 李志明, 宋文会 , 等. 羟基氟硅油改性聚醚型聚氨酯的研究[J]. 化学建材, 2007,23(3):17-19.
[57]	雷海波, 罗运军, 李晓萌 , 等. 织物涂层用含氟硅油改性聚氨酯水分散体的合成与表征[J]. 高分子材料科学与工程, 2012,28(4):26-30.
[58]	左勇, 郝海霞, 谢洪德 . 氨基氟硅油改性水性聚氨酯的研究[J]. 能源化工, 2016,37(1):65-70.
[59]	DU Y, YANG Z H, ZHOU C . Study on waterborne polyurethanes based on poly(dimethyl siloxane) and perfluorinated polyether[J]. Macromolecular Research, 2015,23(9):867-975.
[60]	RENGASAMY S, MANNARI V . Hydrophobic and oil-resistant coatings based on advanced green polyurethane dispersions[J]. Journal of Applied Polymer Science, 2013,130(6):3874-3884.
[61]	王文娟 . 有机氟、硅阻燃水性聚氨酯的合成及性能研究[D]. 青岛:青岛科技大学, 2014.
[62]	刘宁 . 有机氟硅改性聚氨酯单体、聚合物的合成及性能研究[D]. 济南:山东大学, 2012.
[63]	刘舒 . 有机氟硅对聚氨酯乳液性能的影响研究[D]. 济南:山东大学, 2014.
[64]	DAI J B, ZHANG X Y, CHAO J , et al. A new core-shell type fluorinated acrylic and siliconated polyurethane hybrid emulsion[J]. Journal of Coatings Technology and Research, 2007,4(3):283-288.
[65]	潘季荣, 肖新颜, 黄森 . 含氟硅聚氨酯-丙烯酸酯复合乳液的合成[J]. 高分子材料科学与工程, 2012,28(8):1-4.
[66]	YU F F, XU X Y, LIN N B , et al. Structural engineering of waterborne polyurethane for high performance waterproof coatings[J]. RSC Advances, 2015,5(89), 72544-72552.
[67]	TAN H, GUO M, DU R N , et al. The effect of fluorinated side chain attached on hard segment on the phase separation and surface topography of polyurethanes[J]. Polymer, 2004,45(5), 1647-1657.

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