涂料工业 ›› 2013, Vol. 43 ›› Issue (4): 70-73.

• 应用研究 • 上一篇    下一篇

蓖麻油改性环氧基聚脲底漆的研究

张 虎,张伶俐,陈博远,李国荣,廖昔虬,纪凤龙   

  1. 广州秀珀化工股份有限公司,广州 511495
  • 出版日期:2013-04-30 发布日期:2019-05-31
  • 作者简介:张虎(1986—),硕士,主要从事丙烯酸合成、环氧和聚氨酯(脲)体系的研究开发。

Research on Castor Oil Modified Epoxy Primer for Polyurea

Zhang Hu, Zhang Lingli,Chen Boyuan, Li Guorong, Liao Xiqiu, Ji Fenglong   

  1. Zhang Hu, Zhang Lingli, Chen Boyuan, Li Guorong,Guangzhou SUPE Chemical Co. ,Ltd., Guangzhou 511495, China
  • Online:2013-04-30 Published:2019-05-31

摘要: 采用蓖麻油、硅烷偶联剂等制备了聚脲专用环氧树脂底漆。在底漆的成膜过程中,蓖麻油能与基材形成氢键,同时与聚脲层中残留的异氰酸根(—NCO)反应,起到桥接作用,降低了漆膜的内应力,改善了漆膜柔韧性、耐冲击性,提高了粘结强度及耐剥离性能。

关键词: 蓖麻油, 环氧树脂, 底漆, 耐剥离, 内应力

Abstract: Apropnetary epoxy primer for polyurea was prepared with castor oil, silane coupling agent, etc. In the film-forming process, castor oil's hydroxyl was bonded on substratevia hydrogen bond, which also reacted with the residual isocyanate group (-NCO) in polyurea layer, forming a bridge, reducing the internal stress of the paint film and improving the film flexibility, impact resistance, bonding strength and peel resistance.

Key words: castor oil, epoxy resin, primer, peel resistance, internal stress