涂料工业 ›› 2009, Vol. 39 ›› Issue (3): 1-5.

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可膨胀石墨在膨胀型钢结构防火涂料中的应用研究

王国建1,2,纪振鹏2   

  1. 1、先进土木工程材料教育部重点实验室, 上海 200092;2、同济大学材料科学与工程学院,上海 200092
  • 出版日期:2009-03-01 发布日期:2019-05-31
  • 作者简介:王国建(1953—),男,教授,博士生导师,主要从事高分子活性聚合、高分子功能材料、高分子化学建材、涂料等方面的教学和研究。
  • 基金资助:
    国家高技术研究发展计划(863计划)项目,编号:2006AA03Z463

Study on Application of Expandable Graphite in Intumescent Fire-Retardant Coatings for Steel Structures

Wang Guojian1,2,Ji Zhenpeng2   

  1. 1、Key Laboratory of Advanced Civil Enginering Materials,Ministry of Education,Shanghai 200092,China; 2、School of Materials Science and Enginering,Tongji University,Shanghai 200092,China
  • Online:2009-03-01 Published:2019-05-31

摘要: 为了克服钢结构防火涂料膨胀发泡层蓬松易脱落和易开裂的缺点,采用可膨胀石墨来改善防火涂料发泡 层的结构。研究了可膨胀石墨对发泡层形貌和钢结构耐火极限的影响。结果表明,可膨胀石墨膨胀后成“蠕虫”状穿 插于发泡层中,起到增强作用,使炭质层结构更致密。采用膨胀容积为 180mL/g、粒径为 0.18mm、起始膨胀温度为 150°C的可膨胀石墨时,当添加量为 3%时具有较好的改性作用。

关键词: 防火涂料 , 可膨胀石墨 , 膨胀容积 , 粒径 , 起始膨胀温度

Abstract: Expandable graphite (EG) was applied to improve the structure of char layer of the ultrathin fire -retardant coatings and its drawbacks of easy breaking off and cracking. The influence of EG on the fire-retardant property and the morphology of expanded char layer was discussed. The results showed that EG inserted into the char with a"worm-like structure and served as reinforeed substance and made the char layer denser. It was suitable for the modification of fire retardant coatings when 3% of EG with particle 0. 18 mm size, expansion volume 180ml/g and intumescent starting temperature 150℃ was used.

Key words: fire-retardant coatings, expandable graphite, expansion volume, particle size, intumescent starting temperature