摘要： 以阴离子与非离子表面活性剂作为复合表面活性剂, 反应过程中控制纳米 TiO2乳液的 pH 值在 8~ 10, 采用乳液聚合法制备了以纳米 TiO2为核, 聚甲基丙烯酸甲酯 - 丙烯酸丁酯 - 甲基丙烯酸 ( P[ ( MMA- BA ) - MAA] )为壳的杂化复合粒子。用透光率和亲水亲油实验来检验复合粒子在有机溶剂中的分散性, 并借助于 TEM, FT- IR表征了复合粒子的形貌和结构。
关键词:
纳米 TiO2,
复合粒子,
乳液聚合
Abstract: The title core- shell structure nanocomposite particles were prepared by emulsion polymerization with anion ic and nonionic compound surfactant at pH value 8~ 10. The experiments of light transm i-ttance and hydroph ile- lipophilew ere used for detecting the dispersibility o f particles in organic solven.t Themorphology and structure of the hybrid composite particles were characterized by TEM and FT- IR.
Key words:
nano- titanium dioxide,
composite particles,
emulsion polymerization
张建民, 汪志勇, 孙秀果, 彭 政. 纳米二氧化钛核 /聚甲基丙烯酸甲酯 - 丙烯酸丁酯 -甲基丙烯酸壳杂化复合粒子的制备[J]. 涂料工业, 2006, 36(8): 17-20.
Zhang Jianm in, Wang Zhiyong, Sun Xiuguo, Peng Zheng. Preparation of Nano- Titan ium D ioxide P(MMA- BA) - MAA(Core/Shell) Hybrid Composite Particles[J]. Paint & Coatings Industry, 2006, 36(8): 17-20.