Research & Development

Effect of Surface Pretreatment on Interfacial Adhesion between Ceramic-reinforced Epoxy Coatings and Stainless Steel

  • LI Wei ,
  • GE Lianwei ,
  • NIE Zhenhua ,
  • BIAN Chunhua ,
  • LIU Hongqun
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  • 1. CNNC Nuclear Power Operations Management Co., Ltd., Jiaxing, Zhejiang 314000, China; 

    2. Suzhou Nuclear Power Research Institute, Suzhou, Jiangsu 215004, China

Online published: 2026-04-30

Abstract

[Objective] To optimize the interfacial adhesion between ceramic-reinforced resin coatings and stainless steel,and to reveal the intrinsic correlation mechanism linking surface pretreatment,interfacial microstructure,and adhesion performance.[Methods]This study investigated the effects of three pretreatment processes,namely as-manual grinding,mechanical grinding,and sandblasting. Confocal microscopy,X-ray photoelectron spectroscopy(XPS), and scanning electron microscopy/energy dispersive spectroscopy(SEM/EDS)were used to characterize the microtopographyof the stainless steel surface and coating interface. Combined with pull-off tests to measure the coatingadhesion,the adhesion enhancement mechanism and interfacial failure modes were analyzed. [Results]Due to the presence of a dense oxide film(Cr2O3,Fe3O4)on the original surface,gaps were easily formed between the coating and the substrate,resulting in the lowest coating adhesion(4. 9 MPa),the failure was primarily attributed to delamination between the coating and the substrate interface. By removing part of the oxide film and forming grooves,manual/mechanical grinding increased the adhesion to 15. 4-18. 0 MPa by virtue of mechanical interlocking and the stress regulation effect of ceramic phases,and the failure mode presented a mixed pattern of interfaceseparation and coating cohesive failure. Sandblasting removed the oxide film and formed three-dimensional pits,allowing the ceramic phase to interlock deeply with the pits,resulting in peak adhesion.[Conclusion] Surface pretreatment could significantly alter the interfacial microstructurebetween the metal substrate and the coating,ultimately affecting the bonding strength and final failuremode of coating. Sandblasting was the optimal pretreatment process,providing a scientific basis for theselection of pretreatment processes for ceramic-reinforced resin coatings in engineering practice.

Cite this article

LI Wei , GE Lianwei , NIE Zhenhua , BIAN Chunhua , LIU Hongqun . Effect of Surface Pretreatment on Interfacial Adhesion between Ceramic-reinforced Epoxy Coatings and Stainless Steel[J]. Paint & Coatings Industry, 2026 , 56(6) : 9 -15 . DOI: 10.12020/j.issn.0253-4312.2025-349

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