Research & Development

Preparation of Propyl Gallate Modified TiO2 Applied in Antibacterial Coatings

  • TANG Lianxian ,
  • WANG Xiaoge ,
  • ZHANG Guangyu ,
  • XU Zhe ,
  • CHEN Qing ,
  • ZHU Zhongju ,
  • WANG Wei ,
  • ZHAO Xin ,
  • JIN Qichun ,
  • QI Gongwei ,
  • WANG Yaqian
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  • 1. Jinhua Metrological Quality Research Institutel, Jinhua, Zhejiang 321000, China; 

    2. Zhejiang Fangyuan Test Group Co., Ltd., Hangzhou 310018, China; 

    3. China Academy of Building Research, Beijing 100013, China

Online published: 2026-03-02

Abstract

[Objective] To achieve simple and efficient modification of TiO2 to improve the mechanical properties and durability of TiO2 antibacterial coatings.[Methods]TiO2 modification can be achieved by adding propyl gallate directly during the coating preparation without adding additionalorganic solvents. Infrared spectroscopy and X-ray photoelectron spectroscopy were used to study themechanism of the interaction between propyl gallate and TiO2,and the effects of propyl gallate addition on the microscopic morphology,tensile properties and antibacterial properties of the obtained TiO2 antibacterial coatings were studied.[Results] TiO2 surface defects have a weak coordination interaction with propyl gallate. After modification,TiO2 retains some active sites that can participate inphotocatalytic reactions while significantly improving the mechanical properties of the coating. Thereare two principles:when the addition of propyl gallate is less(1. 0%),the dispersion of TiO2 particles in the aqueous phase can be improved,so that the epoxy particles can be evenly distributed during thecuring process and enhance the tensile properties of the coating,and have little impact on the antibacterial properties of the coating(the antibacterial rate is only reduced by 0. 84%); When the addition of propyl gallate was more(2. 5%), the tensile strength and elongation at break could beimproved by enhancing the interfacial binding between TiO2 particles and epoxy resin and inhibiting the two-phase separation,but it also covered the active sites on TiO2 surface,resulting in a decrease in antibacterial performance(4. 77% reduction in antibacterial rate).[Conclusion] Compared with conventional TiO2 dispersants,the appropriate addition of propyl gallate can improve the tensile propertiesand antibacterial properties of the coatings,and can meet the application requirements of relevant primers.The coordination modification strategy of propyl gallate is both economical and efficient,and can provide a technical reference for the industrial production of TiOantibacterial coatings. 

Cite this article

TANG Lianxian , WANG Xiaoge , ZHANG Guangyu , XU Zhe , CHEN Qing , ZHU Zhongju , WANG Wei , ZHAO Xin , JIN Qichun , QI Gongwei , WANG Yaqian . Preparation of Propyl Gallate Modified TiO2 Applied in Antibacterial Coatings[J]. Paint & Coatings Industry, 2026 , 56(4) : 1 -6 . DOI: 10.12020/j.issn.0253-4312.2025-203

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