Research & Development

Research on the Synthesis and Properties of Polyamide Epoxy Curing Agent Based on Michael Addition

  • ZHAO Lianying ,
  • YUAN Ziqing ,
  • WANG Leijie ,
  • YU Jiayao ,
  • SHEN Liang ,
  • HE Haifeng
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  • 1. Department of Coatings and Polymers,School of Chemistry and Chemical Engineering,Jiangxi Normal University of Science and Technology,Nanchang 330013;

    2. Jiangxi Water-based Coating Engineering Research Center,Nanchang 330013,China

Online published: 2026-02-06

Abstract

[Objective]The objective of this study is to prepare a fast-drying,medium-resistant, and tough polyamide-based aqueous epoxy curing agent.[Methods] A polyamide intermediate containing three terminal amine groups(JXA-4D) was first synthesized in one step via a Michael addition reaction using maleic anhydride(MA)and 4,4'-diaminodicyclohexylmethane(H12MDA)as raw materials. Subsequently,the polyamide waterborne epoxy curing agent(MK-165)was synthesized from JXA-4D,a composite polyamine,epoxy resin(NPEL-128), and polyethylene glycol diglycidyl ether(PEGDGE). The thermal properties of MK-165 were then analyzed.[Results]The FT-IR results showed that JXA-4D and MK were successfully synthesized. The prepared JXA-4D exhibited a short-chain high-branched structure with three terminal amine groups. Its low viscosity and high amine valuesignificantly improved reactivity and crosslinking density. MK-165,synthesized from JXA-4D curedNPEL-128 had a stable synthesis process and showed good universality to a variety of epoxy primers.The two-component waterborne epoxy coating prepared with MK-165 exhibited excellent mechanicalproperties,with the cured film achieving both high hardness(3H)and good flexibility(1 mm bend test). The curing speed was fast,the working time was 4 h at room temperature,while maintaining curability in low-temperature environments. Furthermore,the coating demonstrates long-lasting media resistance,including 720 hours of salt spray resistance and 960 hours of water resistance.[Conclusion] A polyamide curing agent was successfully prepared based on the Michael addition method. Whenapplied in two-component coatings,the hardness and curing speed of the coatings were effectively maintained. These findings provided a useful theoretical basis and research foundation for the subsequent development of novel polyamide curing agents.

Cite this article

ZHAO Lianying , YUAN Ziqing , WANG Leijie , YU Jiayao , SHEN Liang , HE Haifeng . Research on the Synthesis and Properties of Polyamide Epoxy Curing Agent Based on Michael Addition[J]. Paint & Coatings Industry, 2026 , 56(3) : 18 -26 . DOI: 10.12020/j.issn.0253-4312.2025-197

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