Green and Low-carbon

Preparation and Properties of Tung Oil-based Waterborne UV-curable Latex Coatings

  • LI Danni ,
  • SHEN Daohai ,
  • RONG Liping ,
  • LI Kexin ,
  • LI Zhiguo
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  • 1. College of Material Science and Engineering,Northeast Forestry University,Harbin 150040,China;
    2. Hangzhou Dasuo Technology Co.,Ltd.,Hangzhou 311251,China;

    3. Institute of Petrochemistry Heilongjiang Academy of Sciences,Harbin 150040,China


Online published: 2026-01-19

Abstract

[Objective]Solve the problems of slow film formation and low adhesion of tung oil-based waterborne coatings.[Methods]A method for preparing UV-curable tung oil-based waterbornelatex coatings was proposed by using double bond functionalized tung oil and polyvinyl acetatelatex/polystyrene(PVAc/PS) core-shell latex via external emulsification composite. By utilising themorphological effects of core-shell latex particles to accelerate the film-forming and water-drainageprocesses of the latex,and combining this with the UV-curing properties of modified tung oil,the curing rate and film properties of the waterborne latex were improved.[Results]Taking pentaerythritol triacrylate(PETA)modified tung oil composite latex as the research object,after adjusting the water-oil ratio and optimizing the emulsifier dosage,combined with particle size distribution and microstructure analysis,it was found that when the emulsifier addition amount was 6% and the water-oil ratio was 7∶3,the latex exhibited uniform particle size dispersion and excellent stability. UV-curingperformance tests showed that high oil phase or high emulsifier addition amount could shorten thecuring time,rapid UV-curing could be achieved in as fast as 22 seconds,and the UV-curing efficiencywas excellent. When the oil phase proportion was high or the emulsifier content was high,the peak value of the stress-strain curve of the paint film was high,the adhesion was stably maintained at level 1 or 0,and at the same time,the gloss was improved and the roughness was reduced.[Conclusion] Through the coordinated control of the water-oil ratio and emulsifier,tung oil-based waterborne latex coatings with good dispersion stability,rapid UV-curing and adjustable film properties can be prepared,providing technical support for the application of natural vegetable oil-based environmentallyfriendly coatings.

Cite this article

LI Danni , SHEN Daohai , RONG Liping , LI Kexin , LI Zhiguo . Preparation and Properties of Tung Oil-based Waterborne UV-curable Latex Coatings[J]. Paint & Coatings Industry, 2026 , 56(5) : 39 -46 . DOI: 10.12020/j.issn.0253-4312.2025-298

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