Green and Low-carbon

Preparation and Properties of Bio-based Polyacrylate Aqueous Dispersions and Coating

  • SHI Haipeng ,
  • WANG Yang ,
  • XU Jie ,
  • WANG Shaochen ,
  • GU Guangxin ,
  • XUE Guoming
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  • 1. College of Environmental and Chemical Engineering,Shanghai University of Electric Power,Shanghai 201306,China;
    2. College of Smart Materials and Future Energy,Fudan University;State Key Laboratory of Coatings for Advanced Equipment,Shanghai 200438,China;

    3. Faculty of Innovation Engineering,Macau University of Science and Technology,Macau 999078,China

Online published: 2025-12-23

Abstract

[Objective]To solve the high reliance of polyacrylate water dispersion on petroleum-based chemicals in the production process,a low-carbon and environmentally friendly preparation route for acrylate was developed.[Methods] In this study, vanillin acrylate(VA) and tetrahydrogeraniol acrylate(THGA)were used to replace traditional petroleum-based compounds toprepare different bio-based acrylate water dispersions and coatings. The influence of bio-based monomers on the performance of the products was investigated,and the renewable carbon content of the products was gradually increased.[Results] The bio-based acrylic water dispersion(PMAIV) prepared with 25%VA and the dispersion(PMAIVT) prepared from 25%VA and 30%THGA allindicated good storage stability. The particle size distribution was uniform,and the prepared paint film indicated high thermal stability. The renewable carbon contents were 24. 99% and 51. 24%, respectively.[Conclusion]The two types of bio-based acrylic water dispersions obtained indicatedgood storage stability and mechanical stability. The resulting paint films showed good physical andmechanical properties and high gloss,providing a new route for the development of low-carbon andenvironmentally friendly waterborne acrylic coatings.

Cite this article

SHI Haipeng , WANG Yang , XU Jie , WANG Shaochen , GU Guangxin , XUE Guoming . Preparation and Properties of Bio-based Polyacrylate Aqueous Dispersions and Coating[J]. Paint & Coatings Industry, 2026 , 56(1) : 53 -61 . DOI: 10.12020/j.issn.0253-4312.2025-127

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