［Objective］To solve the failure of conventional inhibitor at high-temperature duringthe curing addition silicone rubber by dip-coating processes，this study aimed to develop a novel crosslinking inhibitor with broad temperature adaptability.［Methods］ The inhibition effects of bidentate Schiff-base inhibitors（In-2 to In-7）were comparatively investigated and compared with the commonly used acetylene alcohol inhibitor（In-1） in the liquid silicone rubber curing process. A systematic evaluation of coordination atom types（N^N，N^O，N^S）and substituent effects on inhibition performance was conducted through storage stability at 80 ℃，curing time at vulcanization temperature， swelling properties and mechanical properties of cured products.［Results］The N^N type Schiff-base inhibitor In-4 demonstrated optimal performance，extending the storage time at 80 ℃ from 2 h to 6 hwhile maintaining superior mechanical properties with the tensile strength and elongation at breakbeing 3. 34 MPa，317% respectively，at 0. 10 mmol loading. A functional coating with 0. 57 mmthickness was easily achieved by dip-coating for 60 seconds and met most requirements.［Conclusion］ The In-4 inhibitor suppressed effectively the hydrosilylation reaction at 80 ℃，and improved significantly in processing stability. The results above showed great potential applications in dip-coating field. The systematic studies also provided crucial process parameters for high-performancesilicone rubber production.