Research & Development

Preparation and Antifouling Properties of Benzisothiazolinone-copper Acetate Resin

  • SHENG H W ,
  • LIU X Y ,
  • DONG M ,
  • et al
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  • Key Laboratory of Green Catalysis and Reaction Engineering of Haikou,School of Chemistry and Chemical Engineering,Hainan University,Haikou 570228,China

Online published: 2025-09-17

Abstract

[Objective] This study aimed to develop a new resin material combining efficientmarine antifouling performance with stable mechanical properties.[Methods] A novel copper-containing functional monomer(BIT-copper acetate)was prepared by innovatively combining 1,2-benzisothiazol-3-one(BIT)with a copper compound. Subsequently,through free radical polymerization, the monomer was then grafted at varying contents onto the side chain of acrylic resin to prepare the newBIT-copper acetate resin. The structures of the synthesized monomer and resin were characterizedusing 1H NMR and FT-IR spectroscopy. The antifouling performance was evaluated by algae andbacterial inhibition tests as well as a 60-day real-sea hanging plate test.[Results]The resin exhibited excellent inhibitory effects against three species of algae and two species of bacteria,with a maximum algae inhibition rate of 80% and a bacteriostasis rate close to 100%. The 60-day real-sea hanging plate test confirmed its good antifouling performance in a real marine environment. The optimal foulinginhibition was achieved when the BIT-copper acetate content was around 10%,and no cracking or peeling was observed on the coating surface.[Conclusion]The prepared BIT-copper acetate resindemonstrated both high antifouling efficiency and stable mechanical properties.

Cite this article

SHENG H W , LIU X Y , DONG M , et al . Preparation and Antifouling Properties of Benzisothiazolinone-copper Acetate Resin[J]. Paint & Coatings Industry, 2025 , 55(10) : 17 -22 . DOI: 10.12020/j.issn.0253-4312.2025-198

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