Technology

Synthesis of Fluoroalcohol Modified Polyurethane Acrylate and Hydrophobicity and Wear Resistance of Its Coating

  • LI J X ,
  • MA Y ,
  • QU M J ,
  • et al
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  • 1. School of Chemical Engineering,Dalian University of Technology,Dalian,Liaoning 116024,China;
    2. Yingde Amalchem Polymer New Material Co., Ltd., Yingde,Guangdong 513000,China

Online published: 2025-05-23

Abstract

[Objectives] To enhance the hydrophobicity and wear-resistance of polyurethane acrylate matrix,and expand its application in high-end electronics field.[Methods] A series of fluorinated polyurethane acrylate(FPUA)resins were synthesized using toluene diisocyanate(TDI), polycaprolactone diol(PCL),octafluoropentanol(OFP)and 2-hydroxyethyl methacrylate(HEMA),and the resins were then mixed with multifunctional reactive diluents and photoinitiators to form photocurable coatings. The resin with different amount of fluoroalcohol and the cured coating weretested.[Results]The addition of the monofluoroalcohol OFP reduced the surface tension of FPUA coating,which made the coating have excellent hydrophobicity. When the OFP content was 20%,the water contact angle could reach 99° . The introduction of OFP made the coating have good hydrophobicity under different friction times,as well as excellent mechanical properties includingadhesion grade 0,hardness 2H,and impact resistance 50 cm.[Conclusion]The introduction of OFP improved the hydrophobicity and wear-resistant performance of polyurethane acrylate,providing a feasible idea for its application in the field of low surface energy.

Cite this article

LI J X , MA Y , QU M J , et al . Synthesis of Fluoroalcohol Modified Polyurethane Acrylate and Hydrophobicity and Wear Resistance of Its Coating[J]. Paint & Coatings Industry, 2025 , 55(6) : 28 -35 . DOI: 10.12020/j.issn.0253-4312.2025-028

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