Research & Development

Effect of Acrylate on Heat Resistance of Silicone Pressure-sensitive Adhesives

  • HU Y C ,
  • QIAN L ,
  • XIONG L P ,
  • et al
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  • 1. School of Materials Science and Engineering,East China Jiaotong University,Nanchang 330013,China;

    2. Jiangxi New Jiayi New Materials Co., Ltd., Jiujiang,Jiangxi 330300,China

Online published: 2025-04-08

Abstract

[Objective]To solve the difficulties of synergistic improving the heat resistance andbonding performance in the study of high-temperature resistance modification of silicone pressure-sensitive adhesives(SPSA).[Methods]A series of modified crosslinkers were successfully prepared by grafting methyl acrylate,benzyl acrylate,and tetrahydrofurfuryl acrylate onto hydrogen-containingcrosslinkers through hydrosilylation reaction. By adjusting the dosage of these modified crosslinkers, the 180° peel strength,loop tack,cohesive strength,and high-temperature residual adhesive content ofSPSA were systematically evaluated to analyze the impact of modification on bonding performance andheat resistance.[Results]The introduction of acrylates significantly enhanced the bonding ability of SPSA. Specifically,benzyl acrylate-modified SPSA exhibited high peel strength(>3. 67 N/cm)and loop tack(>12. 675 N)while elevating the residue-onset temperature to 280 ℃,greatly enhancing heat resistance.[Conclusion]This work achieved synergistic optimization of bonding performance and heat resistanc in SPSA. The application of benzyl acrylate-modified crosslinkers provided an effectivesolution to address high-temperature residue and insufficient adhesion,which was conducive to expanding the engineering applications of SPSA in high-temperature environments.

Cite this article

HU Y C , QIAN L , XIONG L P , et al . Effect of Acrylate on Heat Resistance of Silicone Pressure-sensitive Adhesives[J]. Paint & Coatings Industry, 2025 , 55(5) : 8 -15 . DOI: 10.12020/j.issn.0253-4312.2024-385

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