Diallyl eugenol（2A-EU）and tetrathioglycoluril（TMGU）were prepared from eugenol and glycoluril，respectively. A series of thiol-ene UV curable coatings was prepared by adjusting n（2A-EU）∶n（TMGU）， and their heat resistance，curing behavior，coating properties，thermodynamic properties and mechanical properties were studied. Finally，the effects of n（C=C）∶n（— SH）on the properties of the coatings were investigated. The resultsshowed that with the increase of TMGU dosage，the crosslinking network was denser after curing. The glass transition temperature（T_g）of the coating increased from 22 ℃ to 50 ℃，while the initial thermal decomposition temperature（T_5%）increased from 220. 8 ℃ to 288. 5 ℃ and the tensile strength increased from 0. 67 MPa to 15. 79 MPa. The UV-curing coating had good transparency and adhesion to glass.