Study on the Preparation and Properties of High Refractive Index TiO2 Nano-Hybrid Material

HU Xu-Can; TAO Ba-Mang; LIU Jia-Cheng; CHEN Kun; LIU Jing

doi:10.12020/j.issn.0253-4312.2019.11.24

Paint & Coatings Industry >

2019 , Vol. 49 >Issue 11: 24 - 31

DOI: https://doi.org/10.12020/j.issn.0253-4312.2019.11.24

Study on the Preparation and Properties of High Refractive Index TiO₂ Nano-Hybrid Material

HU Xu-Can ,
TAO Ba-Mang ,
LIU Jia-Cheng ,
CHEN Kun ,
LIU Jing

Expand

School of Chemical and Material Engineering，Jiangnan University，WuXi，Jiangsu 214122，China

Received date: 2019-05-29

Revised date: 2019-10-08

Online published: 2019-11-01

Fold

Abstract

A polymer matrix containing S and Br elements was prepared by means ofthiol-epoxy click chemistry，using epoxy resin of 1，2-ethanedithiol tetrabromobisphenol A and 9，9-Bis[4-（glycidyloxy）phenyl] fluorene as main materials and LiOH methanol solutionas catalyst. The transparent high refractive index TiO₂ nano hybrid materials were prepared by means of sol-gel method and segmental heat curing，using titanium butoxide as precursor andacetylacetone as an alcoholysis control agent. The structure and properties were characterizedby infrared spectroscopy，nanometer particle size analyzer，ellipsometry，transmission electron microscopy and ultraviolet-visible spectrophotometer. The experimental results showed that TiO₂ particles were successfully synthesized and homogeneously dispersed at the nanometerscale in the polymer matrix，and the materials provided high light transmittance in the visible light region，at around 95%. As the amount of hybridization of TiO₂ particles increases，the refractive index at 486 nm increases from 1. 660 2 to 1. 756 5，and the Abbe number increases from 21. 65 to 34. 63.

Key words： refractive index; TiO₂ particles; light transmittance; nano-hybrid materials

Cite this article

HU Xu-Can , TAO Ba-Mang , LIU Jia-Cheng , CHEN Kun , LIU Jing . Study on the Preparation and Properties of High Refractive Index TiO₂ Nano-Hybrid Material[J]. Paint & Coatings Industry, 2019 , 49(11) : 24 -31 . DOI: 10.12020/j.issn.0253-4312.2019.11.24

References

[1] TANGYH，PINA-HERNANDEZ C，NIU Q J，et al.A novel high-refractive index episulfide -thiol polymer for nanoimprinting optical elements[J]. Journal of Materials Chemistry C，2018，10（6）8823-8831.
[2]ALIMMD，GLUGLA D J，MAVILA S，et al.High dynamic range(Δn)two-stage photopolymers via enhanced solubilityof a high refractive index acrylate writing monomer[J].ACSApplied Materials & Interfaces, 2018, 21(3):1217-1224
[3]CODYD，GRIBBIN S，MIHAYLOVA E，et al.Low-toxicityphotopolymer for reflection holography[J].ACS Applied Mate-rials & Interfaces, 2016, 8(28):18481-
[4] HOWF，UDDIN M A，CHAN H P.The stability of high refractive index polymer materials for high-density planaroptical circuits [J]. Polymer Degradation and Stability， 2009，94（2）158-161.
[5]JANICKI V，WILBRANDT S，STENZEL O，et al.Hybridoptical coating design for omnidirectional antireflectionpurposes[J].Journal of Optics A：Pure & Applied Optics, 2005, 7(8):L9-
[6]HIGASHIHARA T，UEDA M.Recent progress in highrefractive index polymers[J].Macromolecules, 2015, 48(7):1915-1929
[7]RIAZ S，BASHIR M，NASEEM S.Synthesis of stabilizedzirconia hollow nanoparticles：sugar as a template[J].Journalof Sol-Gel Science and Technology, 2015, 74(2):275-280
[8]KICKELBICK G.Concepts for the incorporation of inorganicbuilding blocks into organic polymers on a nanoscale[J].Progress in Polymer Science, 2003, 28(1):83-114
[9]RIAZ S，NASEEM S.Controlled nanostructuring of TiO2 nanoparticles：a sol-gel approach[J].Journal of Sol-GelScience and Technology, 2015, 74(2):299-309
[10]BASHIR M，RIAZ S，NASEEM S.Fe3O4 stabilized zirconia： structural，mechanical and optical properties[J].Journal ofSol-Gel Science and Technology, 2015, 74(2):281-289
[11] RAOYQ，DIVID B，CHEN S M，NANCYL F.Nanocompositematerials comprising high loadings of filler materials and anin-situ method of making such materials：US20070042174 [P]. 2007.
[12] SUWF，KUAN Y H.Solventless nontoxic high refractiveindex and low birefringence organic / inorganic hybridmaterials：US6835792[P]. 2004.
[13]MONT F W，KIM J K，SCHUBERT M F，et al.High-refractive-index TiO2 -nanoparticle -loaded encapsulantsfor light-emitting diodes[J].Journal of Applied Physics, 2008, 103(8):2365-2372
[14]王洪梅，赵中一，陈莉莉 .二氧化钛亲水性技术现状 [J].环境与可持续发展， 2003（2）36-39.
[15]武信.法制备纳米二氧化钛及其紫外吸收性能的研究[J].云南冶金, 2011, 40(6):43-45

Options

Outlines

模态框（Modal）标题

Abstract

Cite this article

References