A matt water-borne hydroxyl acrylic dispersion was prepared by drop wise adding amixed solution of methyl methacrylate,butyl acrylate,hydroxyethyl methacrylate,styrene,acrylic acid and an initiator into a pre-prepared solution of glycidyl ester of versatic acid(E10P)and tetrabutyl titanate,and reacted in two steps by bulk polymerization,which was then neutralized with alkali and dispersed with water. The prepared resin was cured with waterborne polyisocyanate curing agent to form a film,and the properties were tested. The results showed that the in-housemade aqueous hydroxy acrylic dispersion provided good comprehensive physical properties,and good water and solvent resistance. The gloss(60°)of clearcoat was between 50~60,with excellent matting effect.
WANG Yuan-You
,
ZHOU Guo-Qiang
. Preparation and Properties of Waterborne Hydroxy Acrylate Dispersion Self-matting Resin[J]. Paint & Coatings Industry, 2019
, 49(10)
: 48
-54
.
DOI: 10.12020/j.issn.0253-4312.2019.10.48
[1]周国强,王元有.酯交换法改性低溶剂羟基丙烯酸分散体的制备及其应用[J].染整技术, 2018, 40(6):33-38
[2] ZHOUGQ,WANG Y Y,GUO J,et al.Preparation and characterization of KPS@ Ppy core-shell microcapsules with controlled release properties[J]. Polymer Bulletin, 2017,74(9)3871-3888.
[3]ZHOUGQWANG Y Y. Preparation and application of modified hydroxyl acrylic dispersion without solvent by a four step synthetic approach[J].[J].Progress in Organic Coatings, 2019, 130:93-98
[4]乔永洛,申亮,余亮亮.水性玻璃漆用高档羟丙树脂的制备及其应用[J].涂料工业, 2013, 43(12):14-18
[5]姚琳,李阿峰,杨黎燕.水性羟基丙烯酸树脂的制备及表结语征[J].应用化工, 2012, 41(5):924-927
[6]胡中,祝宝英,庄振宇,等.高固含量水性羟基聚丙烯酯的制备研究[J].涂料工业, 2011, 41(4):35-38
[7]张发爱,余彩莉,王云普.羟基丙烯酸乳液在水性双组分聚氨酯涂料中的应用[J].涂料工业, 2006, 36(5):5-8
[8]俞剑峰,潘红霞,周晓东.改性丙烯酸树脂的制备及其在水性卷材涂料中的应用[J].化学世界, 2013, 54(6):372-375
[9]周树军.聚酯改性丙烯酸聚氨酯汽车面漆的研制[J].现代涂料与涂装, 2012, 15(4):10-12
[10]钟荆祥,胡中源,郭越超.不饱和聚酯改性丙烯酸树脂及其涂料的研制[J].上海涂料, 2014, 52(3):6-8
[11]张育波,包春磊,王炼石,等.星形超支化聚酯改性丙烯酸酯树脂的制备及其水性涂料性能研究[J].电镀与涂饰, 2012, 31(9):55-58
[12]潘红霞,俞剑峰.卷材涂料用水性丙烯酸树脂的制备及其性能研究[J].上海涂料, 2010, 48(8):20-23