Preparation and Application of Multi-Crosslinking Hydroxyl Acrylate Latex for Wood Varnish

  • TIAN Ying ,
  • JIAO Yong-Luo ,
  • SHEN Liang
Expand
  • 1. Department of polymer and coating,Jiangxi Science & Technology Normal University,Nanchang 330013, China; 2. Jiangxi Engineering Laboratory of Waterborne Coating,Nanchang 330013,China

Received date: 2019-02-27

  Revised date: 2019-05-22

  Online published: 2019-07-01

Abstract

A multi-crosslinking hydroxyl acrylate latex for wood varnish was developed bya semi-continuous emulsion polymerization process,with butyl acrylate(BA) and methyl methacrylate(MMA)as the main monomers,acrylic acid(AA), hydroxyethyl methacrylate(HEMA)and diacetone acrylamide(DAAM)/ adipic acid dihydrazide(ADH)self-crosslinkingsystem as functional monomers. The influence of dosage and glass transition temperature(Tg) of HEMA,DAAM/ADH,AA on latex and film therefrom were investigated. The results showedthat when the hydroxyl groups content was 4%,and DAAM and AA accounted for 2% and 1.5% of the total monomer respectively,and the Tg of latex was 20 ℃(Ca.value),the preparedhydroxyl latex was used to formulate a two-component wood finish. The film showed a pencilhardness of 2H,adhesion of grade 0,excellent water resistance and good chemical resistance.

Cite this article

TIAN Ying , JIAO Yong-Luo , SHEN Liang . Preparation and Application of Multi-Crosslinking Hydroxyl Acrylate Latex for Wood Varnish[J]. Paint & Coatings Industry, 2019 , 49(7) : 53 -58 . DOI: 10.12020/j.issn.0253-4312.2019.7.53

References

[1]刘国杰.国内外水性木器涂料发展现状及趋势[J].现代涂料与涂装, 2014, 17(11):7-13
[2]陈小文,蒋建平,肖国钦.中国水性木器涂料的发展现状及今后 年的技术市场定位[J].中国涂料, 2014, 29(6):9-13
[3]宋羽,郭青,吴蓁.水性丙烯酸酯树脂交联体系的研究进展[J].中国胶黏剂, 2013, 22(5):293-298
[4]伍忠岳,叶荣森,刘志刚.双组分水性木器涂料发展现状及存在问题[J].中国涂料, 2008, 23(1):9-11
[5]张雅莲,陈任.水性木器涂料用自交联型丙烯酸酯乳液的制备与性能研究[J].中国涂料, 2016, 31(7):19-22
[6]商武,袁腾,王锋,等.水性木器涂料用有机硅改性苯丙乳液的合成与性能研究[J].中国涂料, 2013, 28(6):16-21
[7]严文斌,张心亚,朱延安,等 .金属离子交联型丙烯酸酯乳液的研究进展 [J].涂料工业, 2011,41(7)67-70.
[8]李晓东,曾军伟,杨继先.高性能羟丙乳液与应用[J].中国涂料, 2017, 32(6):13-16
[9]陈佳,强西怀.酮肼交联体系核壳丙烯酸树脂乳液的制备及涂膜性能[J].精细化工, 2012, 29(12):1212-1216
[10]张娟,沈一丁,王海花,等.酮肼交联对聚丙烯酸酯乳液及成膜性能的影响[J].功能材料, 2013, 44(2):194-196
Outlines

/