Waterborne epoxy curing agent is an important part of waterborne epoxy system，and its composition and structure play an important influence on the physical and chemical properties of coatings films. In this paper，the types and characteristics of waterborne epoxy curing agents were described，and the general preparation methods and advantages anddisadvantages of ionic and non-ionic waterborne epoxy curing agents were summarized. The effect of the compatibility and reactivity of waterborne epoxy curing agents on the curing films and its control methods were also discussed，which provided guidance for selection of suitable curing agents and development of waterborne epoxy curing agent with excellent performance.
DONG Yu-Qiang
,
JIA Zheng-Bin
. Research Progress in Waterborne Epoxy Resin Curing Agent[J]. Paint & Coatings Industry, 2019
, 49(7)
: 70
-75
.
DOI: 10.12020/j.issn.0253-4312.2019.7.70
[1]WANGN，ZHANG Y N，CHEN J S，et al. Dopamine modified metal-organic frameworks on anti-corrosion properties[J].[J].Progress in Organic Coatings, 2017, 109:126-134
[2]JINFL，LIX，PARK S J. Synthesis and application of epoxy resins：A review[J].[J].Journal of Industrial and Engineering Chemistry, 2015, 29:1-11
[3]GALGOCI E C，KOMAR P C，ELMORE J D.High perfor-mance waterborne coatings based on dispersions of a solidepoxy resin and an amine-functional curing agent[J].Jour-nal of Coatings Technology, 1999, 71(891):45-52
[4]阮韶铭，张爱卿，阮榆 .一种水性环氧树脂固化剂及其制备方法： CN103044856A[P]. 2013-04-17.
[5]王佳淼.环氧树脂的特性与应用领域分析[J].技术与市场, 2016, 23(11):126-
[6]WALKERFH，COOKM I. Two-component waterborne ep-oxy coatings[J].[J].American Chemical Society Symposium, 1997, 663:71-93
[7]陶永忠，陈铤，顾国芳.型水性环氧树脂固化剂及其涂料性能[J].建筑材料学报, 2000, 3(4):349-354
[8]赵金榜.水性环氧固化剂的研发简史及其今后发展方向[J].现代涂料与涂装, 2014, 17(2):28-33
[9] COOK M I.Formulating novel aqueous epoxy resin systemsfor metal primer applications[C]. Nürnberg：Technical Man-ager Europe，2001：132-137.
[10]COOK M I，WALKER F H，DUBOWIK D A.Recent devel-opments in two-pack water-based epoxy coatings[J].Sur-face Coatings International, 1999, 82(11):528-535
[11]刘明，张汉青，祝宝英，等.两步扩链法制备自乳化水性环氧树脂固化剂及其在水性涂料中的应用[J].涂料工业, 2017, 47(12):74-79
[12]邹海良，张亚峰，邝健政，等.水性环氧固化剂及其改性技术[J].热固性树脂, 2010, 25(4):53-57
[13]胡锋，樊庆春，段伟，等.复合封端水性环氧树脂固化剂的合成与性能[J].现代涂料与涂装, 2010, 13(3):1-3
[14]马尚权，康惠花，钱瑞，等.一种水性环氧固化剂的制备与涂膜性能测试[J].华北科技学院学报, 2018, 15(2):93-97
[15]程文杰 .非离子型环氧乳液及固化剂的合成与性能研究[D].武汉：湖北工业大学， 2017.
[16]SUN H，NI W，YUAN B，et al.Synthesis and characterizationof emulsion‐type curing agent of water‐borne epoxy resin[J].Journal of Applied Polymer Science, 2013, 130(4):2652-2659
[17]ZHANG K，HUANG C H，FANG Q J，et al.Synthesis of aself-emulsifiable waterborne epoxy curing agent based on glycidyltertiary carboxylic ester and its cure characteristics[J].Applied Polymer, 2017, 134(6):442-454
[18]钱瑞，马尚权，赵建国，等.自乳化水性环氧固化剂的合成及性能[J].涂料工业, 2018, 48(3):28-33
[19]华成武，邓刚，孟闯，等.水性环氧固化剂分散体的制备与应用[J].河南科学, 2018, 36(5):657-662
[20] POKORSKI，ANDRZEJ.Guring agent for epoxy resins：US， 9988486B2[P]. 2018-06-05.
[21]祝宝英，许飞，张汉青，等.侧链非离子改性水性环氧固化剂的制备及性能研究[J].涂料技术与文摘, 2017, (12):47-51
[22]席发臣，陈小庆，裴国龙，等.水性环氧涂料的研究[J].现代涂料与涂装, 2005, 8(6):4-6
[23]夏范武，王书林，许君栋.交联型氟树脂与涂料性能关系的研究[J].现代涂料与涂装, 2005, (6):2-3
[24]HANSEN C M.Years with solubility parameters—past and future[J].Progress in Organic Coatings, 2004, 51(1):77-84
[25] ZHANG K，HUANG C，FANG Q，et al.Synthesis of a self‐emulsifiable waterborne epoxy curing agent based on glycidyl tertiary carboxylic ester and its cure characteristics[J].Journal of Applied Polymer Science，2017，134（6）.
[26]EHLERS J E，RONDAN N G，HUYNH L K，et al.Theoretical study on mechanisms of the epoxy-amine curing reaction[J].Macromolecules, 2007, 40(12):4370-4377
[27] BARTON A F M.CRC handbook of solubility parameters and othercohesionparameters[M]. NewYork：Routledge，2017.
[28] ELMORE J D，KINCAID D S，KOMAR P C，et al.Waterborne epoxy protective coatings for metal[J]. Journal of Coatings Technology，2002，74（931）63-72.
[29] ELMORE J，CLAEYS-BOUUAERT P，：HEINE F.Storage stable water based epoxy-amine curable systems：US，92219 599[P]. 2015-12-29.
