An anionic waterborne PUD has been prepared by the self-prepared intermediate introduced with side group， polycarbonate segment， polyester segment， sulfonate segment and crosslinking segment. The effects of dosage of intermediate and IPDI， dosage of PCDL and PCL， type of monomer with crosslinking group， dosage of trihydroxymethyl propane on the performance of PUD and waterborne 1k paint thereof were investigated. The results showed that the prepared waterborne paint met the requirements of automotive coatings.
ZHANG Yu-Bei
. The Synthesis of anionic PUD and its application in one-component waterborne paint[J]. Paint & Coatings Industry, 2019
, 49(2)
: 50
-55
.
DOI: 10.12020/j.issn.0253-4312.2019.2.50
[1]陈用烈，杨建文，曾兆华.辐射固化材料及其应用［M］. 北京： 化学工业出版社， 2003
[2]王德海，江棂.紫外光固化材料理论与应用［M］. 北京： 科学出版社， 2001.
[3]杨娟， 成佳辉， 任冬燕.固化涂料研究进展[J].广州化工, 2011, 39(24):7-8
[4]FANG Y， ZOU Y.Synthesis and photo-curing behaviors of silicon-containing (vinyl ether)—(allyl ether) hybrid monomers[J].Polymer International, 2013, 62(11):1624-1633
[5]DECKER C.Kinetic study of light-induced polymerization by real-time UV and IR spectroscopy[J].Journal of Polymer Science Part A： Polymer Chemistry, 2010, 30(5):913-928
[6]JIANG T， HE Y， JIAN Y， et al.Exploration for decreasing the volume shrinkage for photopolymerization[J].Progress in Organic Coatings, 2012, 75(4):398-403
[7]DECKER C.MOUSSA KKinetic study of the cationic photopolymerization of epoxy monomers[J].Journal of Polymer Science Part A： Polymer Chemistry, 2010, 28(12):3429-3443
[8]SANGERMANO M， BONGIOVANNI R， MALUCELLI G， et al.Synthesis and cationic photopolymerization of a new fluorinated oxetane monomer[J].Polymer, 2004, 45(7):2133-2139
[9]SANGERMANOA M， URBINA B A P， DUARTE L B， et al.Synthesis of an epoxy functionalized spiroorthocarbonate used as low shrinkage additive in cationic UV curing of an epoxy resin[J].European Polymer Journal, 2008, 44(4):1046-1052
[10]聂俊， 何勇， 孙梦洲.紫外阳离子光固化研究进展[J].涂料技术与文摘, 2007, 28(10):1-4
[11]CRIVELLO J V.UV and electron beam-induced cationic polymerization[J].Nuclear Instruments ＆ Methods in Physics Research Section B： Beam Interactions with Materials and Atoms, 1999, 151(1-4):8-21
[12]肖善强， 陈其道， 陈明，等.环氧-丙烯酸酯混杂光固化体系的研究[J].高等学校化学学报, 2002, 23(9):1797-1800
[13]徐鹏，孙东成.醛酮树脂改性的阴／非离子型聚氨酯分散体的合成与性能[J].高分子材料科学与工程, 2014, 30(5):6-10
[14]曾文波.水性聚氨酯消光树脂的制备与应用［D］.广州：华南理工大学，2013.
[15]李韶茂.水性聚氨酯分散体的改性研究［D］.广州：华南理工大学，2010.
[16]朱宁香，叶代勇，陈焕钦，等.聚丙烯酸酯改性聚氨酯复合乳液研究进展[J].化工进展, 2007, 26(10):1419-1424
[17]张育波，秦中海，刘冬立，等.具有结构的无溶剂阴／非离子型的合成及其在单组分水性金属漆中的应用[J].涂料工业, 2017, 47(10):65-70
[18]张育波，刘冬立，周其运，等.水性树脂的合成及其在单组分水性金属涂料中的应用[J].中国涂料, 2008, 33(2):30-35
