Using styrene （St）、methyl methacrylate （MMA） and 2-Ethylethyl Acrylate as the main monomers， the hydroxyethyl methacrylate （HEMA）， methacrylic acid （MAA）， diacetone acrylamide （DAAM） and adipic acid dihydrazide （ADH） as the functional monomers， the adhesion of the prepared emulsion film on plastic substrate was modified by MAA and HEMA. The result showed that the cured film based on crosslinking acrylate emulsion exhibited good hardness and adhesion as well as alcohol-resistant wiping performance on PC and ABS sbustrates when the amount of the designed seed emulsion was 3％ of the pre-emulsion， Tg was 60 ℃， MAA， HEMA and DAAM were 3％， 3％ and 4％ respectively of the total monomers.
ZHANG Xin
. Synthesis of Acrylate Emulsion and Its Application on Plastic Substrates[J]. Paint & Coatings Industry, 2019
, 49(1)
: 62
-66
.
DOI: 10.12020/j.issn.0253-4312.2019.1.62
[1]周铭， 庄爱玉， 穆颖，等.塑料涂料的研究现状与展望[J].涂料工业, 2009, 39(12):5-8
[2]廖阳飞， 张旭东.塑料涂料研究进展[J].上海涂料, 2008, (8):14-18
[3]宋晓丽， 陈莹， 王春鹏.种子用量对核壳型聚丙烯酸酯乳液的影响[J].化工新型材料, 2014, 42(3):140-146
[4]范圣强， 李长久.两类羧基单体在丙烯酸酯乳液聚合中的应用性能比较[J].上海涂料, 2004, 42(2):9-11
[5]张洪涛， 于志伟， 甘明德.羧基聚合物乳胶的制备和性质[J].化学与粘合, 1992, (1):1-2
[6]迟蕾， 杜宗良.双丙酮丙烯酰胺的制备及在丙烯酸聚合物中的应用[J].纺织科技进展, 2004, (6):24-26
[7]张庆思， 崔月芝.双丙酮丙烯酰胺参与共聚的聚丙烯酸酯乳液的制备及其应用[J].应用化学, 2001, 18(2):131-133
[8]KOUKIOTIS C G， KARABELA M M， SIDERIDOU I D.Mechanical properties of films of latexes based on copolymers BA／MMA／DAAM and BA／MMA／VEOVA-10／DAAM and the corresponding self-crosslinked copolymers using the adipic acid dihydrazide as crosslinking agent[J].Progress in Organic Coatings, 2012, 75(1-2):106-115
[9]KOUKIOTIS C， SIDERIDOU I D.Synthesis and characterization of latexes based on copolymers BA／MMA／DAAM and BA／MMA／DAAM and BA／MMA／VEOA-10／DAAM and the corresponding 1K crosslinkable binder using the adipic acid dihydrazide as crosslinking agent[J].Progress in Organic Coatings, 2010, 69(4):504-509
