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丙烯酸酯对有机硅压敏胶耐热性的影响

  • 胡英臣 ,
  • 钱 良 ,
  • 熊丽萍 ,
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  • 1. 华东交通大学材料科学与工程学院,南昌330013;

    2. 江西新嘉懿新材料有限公司,江西九江330300

何忠义( 1971—),男,博士,教授,主要研究方向为润滑油添加剂;邮箱: hzy220567@163.com。

网络出版日期: 2025-04-08

基金资助

江西省自然科学基金( 20232ACB204001、20232BAB20408、20224BAB20448、20224ACB204414) 

Effect of Acrylate on Heat Resistance of Silicone Pressure-sensitive Adhesives

  • HU Y C ,
  • QIAN L ,
  • XIONG L P ,
  • et al
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  • 1. School of Materials Science and Engineering,East China Jiaotong University,Nanchang 330013,China;

    2. Jiangxi New Jiayi New Materials Co., Ltd., Jiujiang,Jiangxi 330300,China

Online published: 2025-04-08

摘要

【目的】解决在有机硅压敏胶( SPSA)耐高温改性研究中存在的耐热性与黏结性能难以协同提升的难题。【方法】利用硅氢化反应,分别将丙烯酸甲酯、丙烯酸苯甲酯及丙烯酸四氢呋喃酯分别接枝到含氢交联剂上,成功制备出一系列改性交联剂。调控改性交联剂的添加量,系统测试 SPSA的 180°剥离强度、环形初黏力、内聚力及高温残胶量,分析改性对其黏结性能与耐热性的影响规律。【结果】丙烯酸酯的引入可显著提升 SPSA的黏结能力,其中丙烯酸苯甲酯改性 SPSA在保持高剥离强度( >3. 67 N/cm)和环形初黏力( 12. 675 N)的同时,残胶出现的温度提升至 280 ℃,耐热性大幅增强。【结论】实现了 SPSA黏结性能与耐热性的协同优化,丙烯酸苯甲酯改性交联剂的应用为解决耐高温残胶和黏结不足问题的解决提供了有效途径,有利于拓展 SPSA在高温环境下的工程应用。

本文引用格式

胡英臣 , 钱 良 , 熊丽萍 , . 丙烯酸酯对有机硅压敏胶耐热性的影响[J]. 涂料工业, 2025 , 55(5) : 8 -15 . DOI: 10.12020/j.issn.0253-4312.2024-385

Abstract

[Objective]To solve the difficulties of synergistic improving the heat resistance andbonding performance in the study of high-temperature resistance modification of silicone pressure-sensitive adhesives(SPSA).[Methods]A series of modified crosslinkers were successfully prepared by grafting methyl acrylate,benzyl acrylate,and tetrahydrofurfuryl acrylate onto hydrogen-containingcrosslinkers through hydrosilylation reaction. By adjusting the dosage of these modified crosslinkers, the 180° peel strength,loop tack,cohesive strength,and high-temperature residual adhesive content ofSPSA were systematically evaluated to analyze the impact of modification on bonding performance andheat resistance.[Results]The introduction of acrylates significantly enhanced the bonding ability of SPSA. Specifically,benzyl acrylate-modified SPSA exhibited high peel strength(>3. 67 N/cm)and loop tack(>12. 675 N)while elevating the residue-onset temperature to 280 ℃,greatly enhancing heat resistance.[Conclusion]This work achieved synergistic optimization of bonding performance and heat resistanc in SPSA. The application of benzyl acrylate-modified crosslinkers provided an effectivesolution to address high-temperature residue and insufficient adhesion,which was conducive to expanding the engineering applications of SPSA in high-temperature environments.
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