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高触变高抗流挂双组分水性环氧涂料的制备

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  • 1.江西科技师范大学化学化工学院涂料与高分子系,南昌 330013;

    2.江西省水性涂料工程研究中心,南昌 330013;

    3.江苏富琪森新材料有限公司,江苏南通 226407

网络出版日期: 2024-05-01

Preparation of Two-component Waterborne Epoxy Coatings with High Thixotropy and High Anti-sagging Resistance

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  • 1. The Department of Coatings and Polymeric Materials,College of Chemistry and Chemical Engineering,Jiangxi Science & Technology Normal University,Nanchang 330013,China;

    2. Jiangxi Engineering Laboratory of Waterborne Coating,Nanchang 330013,China;

    3. Jiangsu Fuqisen new material Co., Ltd.,Nantong,Jiangsu 226407,China

Online published: 2024-05-01

摘要

双组分水性环氧涂料具有触变性和抗流挂性不易调节的问题。采用聚氨酯缔合型增稠剂和膨润土复配,并选用乳液型胺固化剂取代常用的水溶性胺固化剂的方式,制备了一款具有高触变、高抗流挂和优异综合性能的双组分水性环氧涂料。研究了增稠剂和流变助剂的种类及用量、胺固化剂的类型对双组分水性环氧涂料的触变性、抗流挂性及其他应用性能的影响规律,结果表明: 6870乳液型胺固化剂与 299增稠剂和 LT膨润土之间存在相互促进作用,当 299增稠剂用量为 0. 5%、 LT膨润土用量为 0. 3%时,搭配 6870乳液型胺固化剂可制得触变指数为 4. 5、抗流挂极限膜厚为 475 μm、综合性能优异的双组分水性环氧涂料。

本文引用格式

李永康, 王佳胜, 刘胜普, 等 . 高触变高抗流挂双组分水性环氧涂料的制备[J]. 涂料工业, 2024 , 54(5) : 49 -54 . DOI: 10.12020/j.issn.0253-4312.2023-283

Abstract

Two-component waterborne epoxy coatings have the problems of difficult adjustment of thixotropy and anti-sagging resistance. In this paper,a two-component waterborne epoxy coatings with high thixotropy,high anti-sagging and excellent comprehensive properties was prepared by the compounding of polyurethane association thickener and bentonite,and the  selecting emulsion-type amine curing agent to replace the commonly used water-soluble amine curing agent. The effects of the type and amount of thickeners and rheological additives,and the type of amine curing agent on the thixotropy,anti-sagging and other application properties of two-component waterborne epoxy coatings were investigated. The results show thatthere was a mutual promotion effect between the 6870 emulsion-type amine curing agent,299 thickener and LT bentonite. When the dosage of 299 thickener was 0. 5% and the dosage of LT bentonite was 0. 3%,with 6870 emulsion-type amine curing agent,it could produce a thixotropic index of 4. 5,anti-sagging limiting film thickness of 475 μm,and excellent comprehensive performance of two-component waterborne epoxy coatings.
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