健康·安全·环境

多重自交联水性丙烯酸树脂分散体的制备及性能研究

展开
  • 1. 郑州中科新兴产业技术研究院,郑州450000; 2. 龙子湖新能源实验室,郑州450000
李玉(1990—),男,硕士研究生,工程师,主要从事水性丙烯酸和环氧树脂的合成与研究。

网络出版日期: 2023-07-01

Preparation and Properties of Multiple Self-crosslinking Waterborne Acrylic Resin Dispersion

Expand
  • 1. Zheng Zhou Institute of Emerging Industrial Technology,Zhengzhou 450000,China;
    2. Longzihu New Energy Laboratory,Zhengzhou 450000,China

Online published: 2023-07-01

摘要

通过不饱和脂肪酸和 N-(甲氧基甲基)丙烯酰胺(NMMA)与环氧树脂(EP-20)反应得到环氧酯,再将环氧酯与乙烯基类单体采用溶液聚合的方式共聚,制备出多重自交联水性丙烯酸树脂分散体。系统研究了环氧酯和甲基丙烯酸的含量,交联单体 NMMA、乙酰乙酸基甲基丙烯酸乙酯(AAEM)、β-明胶蛋白质、不饱和脂肪酸及制备工艺对树脂涂膜综合性能的影响。结果表明:多重自交联水性丙烯酸涂料具备优异的综合性能,表干时间为 28 min,耐水性达 14 d,硬度和附着力分别为 3H和 0级,还表现出良好的耐溶剂性。

本文引用格式

李玉, 袁东明, 吴琼, 等 . 多重自交联水性丙烯酸树脂分散体的制备及性能研究[J]. 涂料工业, 2023 , 53(7) : 52 -60 . DOI: 10.12020/j.issn.0253-4312.2022-384

Abstract

The multiple self-crosslinking waterborne acrylic resin dispersion wasprepared by solution polymerization through epoxy ester and vinyl monomer. The used epoxyester was obtained by the reaction of epoxy resin(EP-20)with unsaturated fatty acid and N-methoxy methacrylamide(NMMA). It was systematically studied for the comprehensiveproperties of the resin film that was influenced by the proportion of epoxy ester and methacrylicacid,crosslinking monomer NMMA,acetoacetoxyethyl methacrylate(AAEM),β -gelatin protein,unsaturated fatty acid or preparation process. The results showed that multiple self-crosslinking waterborne acrylic coatings indicated excellent comprehensive properties,the surface drying time was 28 min,the water resistance was 14 d,the hardness and adhesion were 3H and 0 grade,respectively,and it also exhibited good solvent resistance. 
文章导航

/