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微弧氧化表面的溶胶-凝胶涂料封孔及其耐腐蚀性研究

  • 邱宁 ,
  • 杨国亮 ,
  • 王振芳 ,
  • 陈益坪 ,
  • 金晓锋
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  • 1.国家电网有限公司,北京 100031; 2.国家电网北京市电力局,北京 100031;
    3.国家电网河南电力公司,郑州 450052; 4.国家电网浙江电力有限公司,杭州 310007;
    5.全球能源互联网研究院有限公司,北京 102211
邱宁(1973—),男,硕士,高级工程师,主要从事电工材料的腐蚀与防护研究。

收稿日期: 2019-05-17

  修回日期: 2019-10-11

  网络出版日期: 2019-11-01

The Sealing Treatment with Sol-Gel Coatings Method for Micro-Arc Oxidation Layerand Its Corrosion Resistance

  • QIU Zhu ,
  • YANG Guo-Liang ,
  • WANG Zhen-Fang ,
  • CHEN Yi-Ping ,
  • JIN Xiao-Feng
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  • 1. State Grid Corporation of China,Beijing 100031,China; 2. State Grid Beijing Electric Power Company, Beijing 100031,China; 3. State Grid Henan Electric Power Company,Zhenzhou 450052,China; 4. State Grid Zhejiang Electric Power Company,Hangzhou 310007,China; 5. Golbal energy interconnection research institute Co., Ltd., Beijing 102211,China

Received date: 2019-05-17

  Revised date: 2019-10-11

  Online published: 2019-11-01

摘要

使用紫外光辅助溶胶 -凝胶的光化学工艺,在微弧氧化的铝合金纤维表面涂敷一层封孔层,封孔层能够有效地将多孔的微弧氧化膜封闭,显著提高铝合金纤维的耐腐蚀性能。对微弧氧化后和封孔后的铝合金纤维进行电化学分析,结果显示,封孔后铝合金纤维的腐蚀电位从 -0.651 V正移至 -0.368V。腐蚀电流密度 Icorr从 6.02×10-6 A/cm2降低到 9.58×10-10 A/cm2,极化电阻 Rp从 5.4×103 Ω·cm2增加到 4.5× 104Ω·cm2,紫外光处理过的封孔膜层的腐蚀速率显著降低,铝合金纤维的耐腐蚀性能显著提高。

本文引用格式

邱宁 , 杨国亮 , 王振芳 , 陈益坪 , 金晓锋 . 微弧氧化表面的溶胶-凝胶涂料封孔及其耐腐蚀性研究[J]. 涂料工业, 2019 , 49(11) : 7 -11 . DOI: 10.12020/j.issn.0253-4312.2019.11.7

Abstract

A thin sealing layer was coated on the micro-arc oxidation film of aluminiumalloy fiber by photo-chemical sol-gel method assisted underultraviolet light. The sealing layercould seal the porous micro-arc oxidation film completely,with a significant increase of thecorrosion resistance of aluminium fiber. The corrosion resistance of the micro-arc oxidation film and sealed layer were analysed by electrochemical workstation,the result showed that the corrosion potential of aluminum alloy fiber was positively shifted form -0. 651 V to -0. 368 V. The corrosion current Icorr was decreased form 6.02×10-6 A/cm2 to 9.58×10-10 A/cm2. The polarization impedance Rp was increased from 5.4×103 Ω·cm2 to 4.5×104 Ω·cm2,and the ultraviolet light treated micro-arc oxidation sealing layer provided low corrosion rate,which ensured the beter corrosion resistance property of aluminum fiber.

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