以水性环氧乳液为基体，掺杂改性的石油树脂作为复合乳液，并制备出水性环氧防腐涂料。利用红外光谱仪、激光粒度仪、接触角测量仪、热重分析仪对其结构及性能进行测试表征，同时测试了其干燥时间、耐水性、耐中性盐雾等性能。结果表明：自制的液体石油树脂基水性环氧防腐涂层表干时间和实干时间分别为 26 min和 15 h，力学性能良好， VOC含量仅为 48 g/L，而耐水性和耐中性盐雾试验分别达到 800 h和 840 h，具有良好的耐腐蚀性。
A waterborne epoxy corrosion protective coatings was prepared with waterborneepoxy emulsion as the matrix and mixed with amodified petroleum resin used as hybridemulsion. Its structure and properties were characterized by infrared spectrometer，laser particle size analyzer，contact angle measurement and thermo-gravimetric analyzer. Theperformance was also tested in terms of drying time，water resistance and neutral salt fogresistance. The results showed that the tack-freetime and the thorough dry time of the coatingswere 26 min and 15 h，respectively. The mechanical properties were also outstanding with alow VOC content of only 48 g/L. The water resistance and neutral salt fog test reached 800 hand 840 h respectively，demonstrating excellent corrosion resistance performance.
[1]叶守富.防腐蚀涂料综述(上)[J].上海涂料, 2000, (3):25-28
[2]叶守富.防腐蚀涂料综述(下)[J].上海涂料, 2001, (1):22-24
[3]PACKHAM E D. Adhesive technology and sustainability[J].[J].Journal of Adhesion & Adhesives, 2009, 29:248-252
[4]陈火平，邹志强，甘宇，等 .水性环氧树脂固化剂的研究进展[J].广州化工，2011，39（10）26-32.
[5]刘洋，黄焕，孔振武，等 .环氧树水性化技术进展[J].涂料工业，2009，39（5）19-24.
[6]包哈森 .水性环氧及其固化的合成与性能研究[D].天津：天津大学，2008.
[7]WEGMANN A.Waterborne two component epoxy amine coating systems[J].Polymer Paint Color Journal, 1996, (6):30-381
[8]孔燕，张树永，李红娟 .正十二硫醇自组装单层膜改善环氧涂层腐蚀防护性能的研究[J].[J].化学学报, 2004, 62:1612-1616
[9] XUELL，XU L K，LI Q F.Effect of nano Al pigment on the anticorrosive performance of waterborne epoxy coatings[J].
[10]Journal of Materials Science and Technology，2007，23（4）：563-567.
[11]李进，张良均，童身毅，等.水性环氧树脂的制备与性能研究[J].涂料工业, 2008, 38(1):44-46
[12]HEQEDUS CHARLES R，PEPE FRANK R，DICKENSON JOHN B，et al.Waterborne acrylic-epoxy coatings[J].Journal of Coatings Technology, 2002, 74(927):31-39
[13]VAN WESTING E P M，FERRARI G M，GEENEN F M，et al. In situ determination of the loss of adhesion of barrier epoxy coatings using electrochemical impedance spectroscopy[J].[J].Progress in Organic Coatings, 1993, 23:89-103
[14]VERKHOLANTSEV V V.Colloidal aspects of waterborne epoxy paints[J].Journal of Coatings Technology, 1996, 6825-28.(853):49-57
[15]CHERNAYA A N，FILIMONOVA O N，NIKULIN S S.Modification of petroleum polymer resin from C9 fraction with maleic acid and its application to protecting treatment of wood[J].Russian Journal of Applied Chemistry, 2007, 80(12):2169-2173
[16] LESNYAK V，SHIMAN D，GAPONIK L，et al.Radicalcopolymerization of the C9 hydrocarbon fraction of liquid pyrolysis products with maleic anhydride[J]. Russian Journal of Applied Chemistry，2007，80（5）822-827.
[17]黄军左，张仕森 .C9石油树脂的改性：技术及应用[J].高分子通报，2010，4（11）62-67.
[18]李春生，寿崇琦，C9石油树脂的改性[J].[J].石油化工, 1999, 28:104-106
