涂料工业 ›› 2009, Vol. 39 ›› Issue (8): 15-19.

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功能性光活性稀释剂的合成及光固化性能研究

甄闻远,李云庆,周宏勇,王家喜   

  1. 河北工业大学化工学院,天津 300130
  • 出版日期:2009-08-01 发布日期:2019-05-14

Preparations and Properties of Functional UV Curable Monomers

Zhen Wenyuan, Li Yunging, Zhou Hongyong, Wang Jiaxi   

  1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China
  • Online:2009-08-01 Published:2019-05-14

摘要: 研究了含有噁唑烷酮单元的新型光活性单体的合成及结构表征,考察了反应条件对产物结构的影响。以实时红外光谱法研究了新型光活性稀释剂、复配胶的光聚合行为,结果表明合成的新单体具有很高的光固化活性。还对所配胶的光固化时间、光固化膜的硬度、耐冲击性、凝胶率等性能进行了研究,考察了胶的组成对紫外光固化膜性能的影响。

关键词: 光活性稀释剂, 光固化, 噁唑烷酮

Abstract:

A series of new UV curable monomers containing oxazolidin-2-one fragment were prepared product structure has been investigated and characterized. The effect of reaction condition on .The results from the real-time infrared spectroscopy (ft-ir of the novel UV curable monomer and gel indicated that the obtained monomer is of higher UV activity. In addition, the curing time of Uv-curable gel,pencil hardness, impact strength, gel content of the cured film was examined. The effect of compositions on the properties of UV cured film was discussed.

Key words: UV curable diluent;UV curing, oxazolidin-2-one