涂料工业 ›› 2025, Vol. 55 ›› Issue (10): 37-41. doi: 10.12020/j.issn.0253-4312.2025-176

• 绿色低碳 • 上一篇    下一篇

生物基绿色本征抗菌聚肟氨酯的制备及性能研究

胡峻玮1,2,田 澍2,卢光明2,王 娜*1   

  1. 1. 沈阳化工大学辽宁省特种功能材料合成与制备重点实验室,沈阳110000;

    2. 中国科学院宁波材料技术与工程研究所海洋关键材料全国重点实验室,浙江宁波315201

  • 出版日期:2025-10-01 发布日期:2025-10-01
  • 基金资助:
    辽宁省重点研发项目( 2024JH2/102400046、2024JH2/102400048、2024JH2/102300004) 

Preparation and Properties of Bio-based Green Intrinsic Antibacterial Poly(oxime-urethane)

HU Junwei1,2,TIAN Shu2,LU Guangming2,WANG Na1   

  1. 1. Liaoning Provincial Key Laboratory for Synthesis and Preparation of Special Functional Materials,Shenyang University of Chemical Technology,Shenyang,110142,China;

    2. State Key Laboratory of Advanced Marine Materials,Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo,Zhejiang 315201,China

  • Online:2025-10-01 Published:2025-10-01

摘要: 【目的】开发绿色环保的抗菌树脂。【方法】通过引入具有本征杀菌活性的生物基呋喃官能化扩链剂,设计并制备了一种绿色环保型本征抗菌聚肟氨酯弹性体(PCDU)。【结果】该材料在保持优异力学性能(拉伸强度达 4. 03 MPa,断裂伸长率达 430%)的基础上,展现出色的抗菌性能(24 h抗菌率 100%)和抗黏附性能(藻和蛋白黏附率几乎为 0)。【结论】制备了一种绿色环保的本征抗菌聚肟氨酯,为后续开发海洋本征抗菌涂料提供一定参考。


关键词: 聚肟氨酯, 生物基, 本征抗菌, 绿色环保, 弹性体

Abstract: [Objective] To develop green and environment-friendly antibacterial resin.[Methods]Herein,we report the design and synthesis of a green,intrinsically antifouling polyoxime urethane elastomer(PCDU)by incorporating a bio-based,furan-functionalized chain extender with inherent antibacterial activity.[Results] The resulting PCDU exhibits outstanding mechanical properties(tensile strength up to 4. 03 MPa and elongation at break of 430%), along with excellent antibacterial efficacy(100% inhibition within 24 h)and antifouling performance(nearly zero adhesion of algae and proteins).[Conclusion] A green and environment-friendly intrinsically antibacterial polyoxime urethane was prepared,which provided a certain reference value for the subsequentdevelopment of intrinsically antibacterial marine coatings.

Key words: poly(oxime-urethane), bio-based, intrinsically antibacterial, green environment-friendly, elastomer

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