摘要： 【目的】制备一种具有可控水解能力的丙烯酸硅烷酯树脂，实现防污剂在涂层中的稳定释放，提升自抛光防污涂料的长效防污性能。【方法】在常规丙烯酸硅烷酯树脂的合成路线中引入丙烯酸异冰片酯单体，成功制备了线性水解丙烯酸硅烷酯树脂，对比其与常规丙烯酸硅烷酯树脂在水解速率上的差异。基于线性水解丙烯酸硅烷酯树脂和有机硼防污剂制备了自抛光防污涂料，探究了树脂含量变化对涂料防污性能的影响。【结果】线性水解丙烯酸硅烷酯树脂的抛光速率在 6周期测试中始终稳定在（ 3±1）μm/月，与常规丙烯酸硅烷酯树脂相比表现出良好的水解稳定性。当涂料中的线性水解丙烯酸硅烷酯树脂含量为 32%时，其防污性能最佳，同时兼具良好的基础性能和配套性能。【结论】线性水解丙烯酸硅烷酯树脂有效增强了自抛光涂料的防污性能，使其能够为船舶、海上钻井平台等海洋设施提供长效污损防护。
关键词:
丙烯酸异冰片酯,
线性水解丙烯酸硅烷酯树脂,
4-异丙基吡啶甲基二苯基硼,
自抛光防污涂料
Abstract: ［Objective］To prepare an acrylic silane ester resin with controllable hydrolysis abilityfor the stable release of antifouling agents within the coating，thereby improving the long-term antifouling performance of self-polishing antifouling coatings.［Methods］Isobornyl acrylate monomerwas introduced into the synthesis route of the conventional acrylic silane ester resin to successfullyprepare a linear hydrolyzable acrylic silane ester resin. The difference in hydrolysis rate between thisresin and the conventional one was compared. A self-polishing antifouling coating was prepared basedon the linear hydrolyzable acrylic silane ester resin and an organic boron antifouling agent. The effect ofresin content variation on the coating’s antifouling performance was investigated.［Results］ The polishing rate of the linear hydrolyzable acrylic silane ester resin remained stable at（3±1）μm/month during 6 laboratory test cycles，demonstrating significantly enhanced hydrolysis stability compared to the conventional acrylic silane ester resin. When the content of linear hydrolyzable acrylic silane esterresin in the coating was 32%，the antifouling performance was optimal，along with excellent mechanical properties and coating compatibility.［Conclusion］The linear hydrolyzable acrylic silane ester resineffectively enhances the antifouling performance of self-polishing coatings，enabling long-term foulingprotection for marine facilities such as ships and offshore drilling platforms.
Key words:
isobornyl acrylate,
linear hydrolyzable acrylic silane ester resin,
4-isopropylpyridine diphenylmethylboronate,
self-polishing antifouling coatings
中图分类号:
刘术辉, 张凯, 王效军, 等. 基于线性水解树脂的自抛光防污涂料的制备与性能研究[J]. 涂料工业, 2025, 55(9): 29-34.
LIU S H, ZHANG K, WANG X J, et al. Preparation and Performance of the Self-polishing Antifouling Coatings Based on Linear Hydrolyzable Resins[J]. Paint & Coatings Industry, 2025, 55(9): 29-34.