涂料工业 ›› 2023, Vol. 53 ›› Issue (12): 9-15. doi: 10.12020/j.issn.0253-4312.2023-086

• 探索开发 • 上一篇    下一篇

高性能环氧石墨烯低锌涂料的研制及性能研究

蒋雨生 1,黄佳琪 1,雒新亮 2,饶兴兴 2,谭伟民 2,吴王平 *1   

  1. 1.常州大学机械与轨道交通学院,江苏常州213164;
    2.中海油常州涂料化工研究院有限公司,江苏常州 213016
  • 出版日期:2023-12-01 发布日期:2023-12-01
  • 通讯作者: 吴王平(1985—),男,博士,副教授,主要研究方向为表面技术、智能制造、新能源材料。
  • 基金资助:
    江苏省研究生科研与实践创新计划项目( SJCX22_1429)

Development and Performance Study of High-performance Graphene/Epoxy Coatings with Low Content of Zinc

Jiang Yusheng1,Huang Jiaqi1,Luo Xinliang2,Rao Xingxing2,Tan Weimin2,Wu Wangping1   

  1. 1. School of Mechanical Engineering and Rail Transit,Changzhou University,Changzhou,Jiangsu 213164,China; 
    2. CNOOC Changzhou Paint and Coatings Industry Research Institute Co., Ltd., Changzhou,Jiangsu 213016,China
  • Online:2023-12-01 Published:2023-12-01

摘要: 为解决传统环氧富锌涂料锌粉含量过高导致的涂层起泡、缩孔、机械性能差等问题,对涂料配方进行优化筛选,并添加超高导电性的石墨烯粉体,制备了一种高性能低锌粉含量环氧防腐涂料。并对涂层的附着力、耐冲击性、耐水性、耐中性盐雾性及耐湿热性等性能进行测试。结果表明:用 19. 35%环氧树脂 E-20、2. 15%聚酰胺加成物固化剂、 45%锌粉、 10%滑石粉、 2%触变剂 881B、1%流平剂 AFCONA-3777、0. 5%石墨烯、 20%稀释剂 2033,制备的环氧石墨烯低锌防腐涂料,涂层具有较高的耐冲击性( 50cm)、附着力( 16 MPa)和优异的耐盐雾性( 2 000 h)、耐水性( 2 000 h)和耐湿热性(2 000 h),可应用于苛刻腐蚀环境。

关键词: 环氧富锌涂料, 石墨烯, 低锌, 防腐涂料, 高导电性

Abstract: In order to solve the problems such as blistering,shrinkage and poormechanical performance caused by high content of zinc powder in traditional epoxy zinc-richcoatings,the coating formula was optimized and screened. And adding ultra-high conductivitygraphene powder to develop a high-performance graphenel/epoxy coatings with low content ofzinc. The adhesion,impact resistance,water resistance,neutral salt spray resistance and moisture and heat resistance of the coating were tested. The results showed that the graphene/epoxy anticorrosion coatings with low content of zinc prepared by using 19. 35%E-20 epoxy resin,2. 15% polyamide additive curing agent,45% zinc powder,10% talcum powder,2% thixotropic agent 881B,1% leveling agent AFCONA-3777,0. 5% graphene and 20% diluent 2033,the coatings had excellent impact resistance(50 cm),adhesion(16 MPa), 
excellent salt spray resistance(2 000 h),water resistance(2 000 h)and damp heat resistance(2 000 h),which could be used in harsh corrosive environment. 

Key words: epoxy zinc-rich coatings;graphene;low content of zinc;anticorrosive 

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